The increasing air pollution taking place in virtue of human activity has a novel impact in our health. Heterogeneous photocatalysis is a promising way of degrading volatile organic compounds (VOCs) that makes the quest of new and improved photocatalysts of great importance. Herein, perovskite-related materials ATiO₃ with A = Mg, Ni, Co, Zn were synthesized through an ethylene glycol-mediated root, with ethylene glycol being used as a solvent and ligand. Characterization techniques such as X-ray diffraction (XRD), scanning electron microscopy, and energy dispersive X-ray spectroscopy (SEM/EDX), transmission electron microscopy (TEM), UV-vis spectroscopy, Raman spectroscopy, Fourier transform infrared (FT-IR), and photoluminescence spectroscopy (PL) were used in order to confirm the structure, the nanorod morphology, their absorption in UV-vis, and the separation efficiency of photogenerated charge carriers. The highest photoactivity was observed for ZnTiO₃ in which 62% of toluene was decomposed after 60 min under LED illumination (54 mW/cm²).

Nitric oxide (NO) is a very well-known indoor pollutant, and high concentrations of it in the atmosphere lead to acid rain. Thus, there is great demand for NO sensors that have the ability to work at room temperature. In this work, NiO/SnO₂ heterostructures have been prepared via the polyol process and were tested against different concentrations of NO gas at room temperature. The structural and morphological characteristics of the heterostructures were examined using X-ray diffraction and scanning electron microscopy, respectively, while the ratio of NiO to SnO₂ was determined through the use of energy-dispersive spectrometry. The effects of both pH and thermal annealing on the morphological, structural and gas-sensing properties of the heterostructure were investigated. It was found that the morphology of the heterostructures consisted of rod-like particles with different sizes, depending on the temperature of thermal annealing. Moreover, NiO/SnO₂ heterostructures synthesized with pH = 8 and annealed at 900 °C showed a response of 1.8% towards 2.5 ppm NO at room temperature. The effects of humidity as well as of stability on the gas sensing performance were also investigated.

Physical processes working in parallel with digital ones have transformed the way we view systems and have led to the creation of applications that boost the quality of people’s lives, increase security as well as decrease production costs of goods. Critical to this evolution is the cost decrease in the components of such systems, among which are gas sensors. In this work, a custom-made Co₃O₄ gas sensing element is presented, which can potentially be used as part of a cyber-physical system (CPS) for O₃ monitoring. To investigate its performance, a CPS is developed using low-cost, low-power micro-controller units (MCUs) and comparisons both with the laboratory equipment and commercial off-the-shelf (COTS) ozone sensors are provided. The experiments show that the Co₃O₄ sensor works at room temperature with low input voltage and low power consumption when used with the proposed MCUs. Moreover, an enhanced gas sensing performance against ozone is observed under low-pressure conditions due to the detection of low ozone concentrations (85.90 ppb) and good sensor response (113.1%) towards 1100 ppb O₃. However, the drawbacks that need improvement relate to the kinetics of the charge carriers, which affect the response time and recovery behavior. The effect of humidity needs to be clarified in further works.