The Kışladağ porphyry Au deposit occurs in a middle Miocene magmatic complex comprising three different intrusions and magmatic-hydrothermal brecciation related to the multiphase effects of the different intrusions. Tourmaline occurrences are common throughout the deposit, mostly as an outer alteration rim around the veins with lesser amounts disseminated in the intrusions, and are associated with every phase of mineralization. Tourmaline mineralization has developed as a tourmaline-rich matrix in brecciated zones and tourmaline-quartz and/or tourmaline-sulfide veinlets within the different intrusive rocks. Tourmaline was identified in the tourmaline-bearing breccia zone (TBZ) and intrusive rocks that had undergone potassic, phyllic, and advanced argillic alteration. The tourmaline is present as two morphological varieties, aggregates of fine crystals (rosettes, fan-shaped) and larger isolated crystals and their aggregates. Four tourmaline generations (tourmaline I to IV) have different compositions and substitutions. Tourmaline I in TBZ and INT#1 is distinguished by the highest Fe_tot and enriched in Fe³⁺. Tourmalines II and III occur as fine aggregates, accompanied by the formation of isolated crystals and are characterized by lower Fe_tot and Fe³⁺. Tourmaline IV is characterized by the lowest Fe_tot, enriched in Cl, and has the highest proportion of X-site vacancy among all the tourmalines. Tourmaline I may be attributed to the potassic stage in INT#1 and early tourmaline in TBZ. Tourmalines II and III from INT#1 and the TBZ could be referred to the phyllic stage. The low Fe content in tourmaline is caused by the simultaneous deposition of sulfide minerals. Tourmaline IV from the TBZ and tourmaline II from INT#3 are distinguished by the high X-site vacancy proportion up to the formation of X-site vacant species as well as enriched in Cl; they can be attributed to the argillic stage of the hydrothermal process. The textural and especially chemical data of the tourmaline from the Kışladağ Au deposit provide information on the physico-chemical conditions during the porphyry to epithermal transition and subsequent epithermal overprinting.

The deposit occurs in a mid-Miocene monzonite magmatic complex represented by three different intrusions, namely Intrusion 1 (INT#1), Intrusion 2 (INT#2, INT #2A), and Intrusion 3 (INT#3). Gold mineralization is hosted in all intrusions, but INT#1 is the best mineralized body followed by INT#2. SEM-CL imaging has identified two different veins (V1 and V2) and four distinct generations of quartz formation in the different intrusions. These are: (i) CL-light gray, mosaic-equigranular quartz (Q1), (ii) CL-gray or CL-bright quartz (Q2) that dissolved and was overgrown on Q1, (iii) CL-dark and CL-gray growth zoned quartz (Q3), and (iv) CL-dark or CL-gray micro-fracture quartz fillings (Q4). Fluid inclusion studies show that the gold-hosted early phase Q1 quartz of V1 and V2 veins in INT#1 and INT#2 was precipitated at high temperatures (between 424 and 594 °C). The coexisting and similar ranges of T_h values of vapor-rich (low salinity, from 1% to 7% NaCl equiv.) and halite-bearing (high salinity: >30% NaCl) fluid inclusions in Q1 indicates that the magmatic fluid had separated into vapor and high salinity liquid along the appropriate isotherm. Fluid inclusions in Q2 quartz in INT#1 and INT#2 were trapped at lower temperatures between 303 and 380 °C and had lower salinities between 3% and 20% NaCl equiv. The zoned Q3 quartz accompanied by pyrite in V2 veins of both INT#2 and INT#3 precipitated at temperatures between 310 and 373 °C with a salinity range from 5.4% to 10% NaCl eq. The latest generation of fracture filling Q4 quartz, cuts the earlier generations with fluid inclusion T_h temperature range from 257 to 333 °C and salinity range from 3% to 12.5% NaCl equiv. The low salinity and low formation temperature of Q4 may be due to the mixing of meteoric water with the hydrothermal system, or late-stage epithermal overprinting. The separation of the magmatic fluid into vapor and aqueous saline pairs in the Q1 quartz of the V1 vein of the INT#1 and INT#2 and CO₂-poor fluids indicates the shallow formation of the Kışladağ porphyry gold deposit.

Individual fluid inclusions with dense carbon dioxide hosted in quartz from the gold-bearing interval penetrated by the SD-3 Kola Superdeep Borehole were studied using modern techniques. The composition and density of the carbon dioxide fluid were determined by Raman spectroscopy and microthermometry. The density of the fluid is 0.37–1.14 g/cm³ and contains minor admixtures of nitrogen (0.3–1.8 mol %) and water (0.1–0.4 mol %). LA-ICP-MS data indicate that the carbon dioxide fluid inclusions contain high concentrations of Au (1–2611 ppm) and Ag (1–4389 ppm), and high-precision optical data indicate that the high-density CO₂ fluid of the inclusions contains Au–Ag nanoparticles. Evidently, gold and silver were transported from the Earth’s mantle to the crust by high-density carbon dioxide fluid in the form of nanoparticles.