Surface-enhanced Raman scattering (SERS) has been widely reported to improve the sensitivity of Raman spectra. Ordinarily, the laser is focused on the sample to measure the Raman spectrum. The size of the focused light spot is comparable with that of micro-nano structures, and the number of micro-nano structures contained in the light spot area (defined as duty cycle) will severely affect the spectrum intensity. In this study, flower-like silver nanostructures were fabricated with a soft lyotropic liquid crystal template in order to investigate the effect of duty cycle. They were observed under a scanning electron microscope, and their spectrum enhancement factor was computed with the obtained Raman spectrum. Then, their duty cycles were measured using a SERS substrate at different locations. A formula was derived to represent the relation between the duty cycle of the nanoflowers and the Raman spectral intensity. This work could promote the actual applications of SERS in high-sensitivity spectrum testing.
This study proposes a simple method of designing a high-speed liquid crystal variable retarder (LCVR) with reflection mode. First, a series of simple formulas is provided for analysing the effects of tilt incidence and birefringence of the liquid crystal on the phase retardation and response time of the LCVR. Then, a reflective LCVR is fabricated to validate the theoretical analysis. Measured results show that the response speed can reach 2.7 kHz with a phase retardation of 1 λ. Furthermore, the theoretical curve is close to the measured curve while the incident angle is less than 10°. However, the theoretical and measured values show a considerable difference under a large incident angle. This problem is discussed, and a modified method is given. This work is helpful for the design and fabrication of high-speed LCVR.
The distribution of metal nanoparticles on the surface of a surface enhancement Raman scattering (SERS)-active substrate plays a prominent part in not only the enhancement of Raman vibration signal, but also the spectrum uniformity. Here, a facile method to fabricate SERS substrates with excellent homogeneity and low cost was proposed, in which a lyotropic liquid crystal soft template was introduced for the coordinated growth of the silver nanoflowers in the process of electrochemistry deposition. Simulation was carried out to illustrate the dominated influence of the distance of electrodes on the deposited nanoparticle number. Two kinds of conductive materials, silver plate and indium tin oxide (ITO) glass, were chosen as the anode, while the cathode was fixed as ITO glass. The simulated conjecture on the effect of electrode flatness on the uniformity of deposited nanoparticles in silver is experimentally proved. More importantly, it was demonstrated that with a relatively smooth and flat ITO glass anode, a SERS substrate featuring higher spectrum uniformity could be achieved. This work is of great significance to the actual applications of the SERS substrate for quantitative detection with high sensitivity.
Aiming at the problem of limited transmission energy of liquid crystal tunable filter (LCTF), a dual-wavelength transmission system with high signal-to-noise ratio (SNR) is proposed in this paper. The proposed transmission factor Qp is the main influence on the number and location of transmission wavelengths as well as the bandwidth of each transmission wavelength for dual-wavelength systems. Dual-wavelength LCTF can improve the effective transmission energy of the system by increasing the number of filtering channels, and the transmission energy can be increased by about 1.8 times and 70% at short and long wavelengths, respectively, which improves the signal-to-noise ratio (SNR) of the system. Moreover, the dual-wavelength LCTF system is even possible to increase the transmission energy by about 7% at a 33% increase in spectral resolution. Therefore, the dual-wavelength LCTF transmission method not only can improve the SNR of target detection with dual-wavelength response features, but also can effectively solve the problem of contradiction between spectral resolution and spectral transmission energy.