An MIL-101(Cr) powder material was successfully prepared using the hydrothermal synthesis method, and then the original MIL-101(Cr) was combined with different mass fractions of CaCl₂ using the immersion method to obtain a MIL-101(Cr)/CaCl₂ composite material. The physical properties of the adsorbent were determined by X-ray powder diffraction (XRD), an N2 adsorption desorption isotherm test, and thermogravimetric analysis (TG). The water vapor adsorption performance of the metal-organic frameworks MOFs was tested with a gravimetric water vapor adsorption instrument to analyze its water vapor adsorption mechanism. Based on the SIMULINK platform in the MATLAB software, a simulation model of the coefficient of performance (COP) and cooling capacity of the adsorption refrigeration system was established, and the variation trends of the COP and cooling capacity of the adsorption refrigeration system under different evaporation/condensation/adsorption/desorption temperatures was theoretically studied. MIL101-(Cr)/CaCl₂-20% was selected as the adsorption material in the adsorption refrigeration system through the physical characterization of composite materials with different CaCl₂ concentrations by means of adsorption water vapor test experiments. A closed adsorption system performance test device was built based on the liquid level method. The cooling power per unit and adsorbent mass (COP and SCP) of the system were tested at different evaporation temperatures (288 K/293 K/298 K); the adsorption temperature was 298 K, the condensation temperature was 308 K, and the desorption temperature was 353 K. The experimental results showed that COP and SCP increased with the increase in the evaporation temperature. When the evaporation temperature was 298 K, the level of COP was 0.172, and the level of SCP was 136.9 W/kg. The COP and SCP of the system were tested at different adsorption temperatures (293 K/298 K/303 K); the evaporation temperature was 288 K, the condensation temperature was 308 K, and the desorption temperature was 353 K. The experimental results showed that the levels of COP and SCP decreased with the increase in the adsorption temperature. When the adsorption temperature was 293 K, the level of COP was 0.18, and the level of SCP was 142.4 W/kg.

Air source heat pumps (ASHPs) are widely recognized as energy-saving and environmentally friendly heating and air-conditioning equipment with broad applications. However, when conventional ASHPs are operated at a low ambient temperature, they suffer from problems such as high discharge temperature and low heating efficiency. To address these problems, this study designed a new type of dual evaporator combined with a compressor casing thermal storage heat pump system (DE-CCTS) on the basis of a low-temperature air source heat pump water heater with enhanced vapor injection (EVI). The proposed DE-CCTS used thermal storage phase change material (PCM), which was filled in the secondary evaporator (the thermal storage heat exchanger), to recover the waste heat of the compressor casing. Unlike that in the original system under different ambient temperatures, the suction temperature increased by 0.1–1 °C, the discharge temperature decreased by 0.1–0.5 °C, and the coefficient of performance (COP) of DE-CCTS increased by 0.85–4.72% under the proposed system. These effects were especially evident at low temperatures.

In this study, the hydrothermal method was used to synthesize MIL-101(Cr), and activated carbon (AC) with different content was incorporated in to MIL-101(Cr), thereby obtaining AC-MIL-101(Cr) composite material with a huge specific surface area. The physical properties of MIL-101(Cr) and AC-MIL-101(Cr) were characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), nitrogen adsorption and desorption and specific surface area testing, and ethanol vapor adsorption performance testing. The results show that with the increase of activated carbon content, the thermal stability of AC-MIL-101(Cr) is improved. Compared with the pure sample, the BET specific surface area and pore volume of AC-MIL-101(Cr) have increased. In the relative pressure range of 0–0.4, the saturated adsorption capacity of AC-MIL-101(Cr) to ethanol vapor decreases slightly. It is lower than MIL-101(Cr), but its adsorption rate is improved. Therefore, AC-MIL-101(Cr)/ethanol vapor has a good application prospect in adsorption refrigeration systems. The exploration of AC-MIL-101(Cr) composite materials in this paper provides a reference for the future application of carbon-based/MOFS composite adsorbent/ethanol vapor working fluid in adsorption refrigeration.