The distribution of water in the Moon’s interior carries implications for the origin of the Moon¹, the crystallization of the lunar magma ocean² and the duration of lunar volcanism². The Chang’e-5 mission returned some of the youngest mare basalt samples reported so far, dated at 2.0 billion years ago (Ga)³, from the northwestern Procellarum KREEP Terrane, providing a probe into the spatiotemporal evolution of lunar water. Here we report the water abundances and hydrogen isotope compositions of apatite and ilmenite-hosted melt inclusions from the Chang’e-5 basalts. We derive a maximum water abundance of 283 ± 22 μg g⁻¹ and a deuterium/hydrogen ratio of (1.06 ± 0.25) × 10^–4 for the parent magma. Accounting for low-degree partial melting of the depleted mantle followed by extensive magma fractional crystallization⁴, we estimate a maximum mantle water abundance of 1–5 μg g⁻¹, suggesting that the Moon’s youngest volcanism was not driven by abundant water in its mantle source. Such a modest water content for the Chang’e-5 basalt mantle source region is at the low end of the range estimated from mare basalts that erupted from around 4.0 Ga to 2.8 Ga (refs. ^5,6), suggesting that the mantle source of the Chang’e-5 basalts had become dehydrated by 2.0 Ga through previous melt extraction from the Procellarum KREEP Terrane mantle during prolonged volcanic activity.

Variations of total water contents were detected in situ from the lunar regolith and rock at the Chang’E-5 landing site.

The past two decades of lunar exploration have seen the detection of substantial quantities of water on the Moon’s surface. It has been proposed that a hydrated layer exists at depth in lunar soils, buffering a water cycle on the Moon globally. However, a reservoir has yet to be identified for this hydrated layer. Here we report the abundance, hydrogen isotope composition and core-to-rim variations of water measured in impact glass beads extracted from lunar soils returned by the Chang’e-5 mission. The impact glass beads preserve hydration signatures and display water abundance profiles consistent with the inward diffusion of solar wind-derived water. Diffusion modelling estimates diffusion timescales of less than 15 years at a temperature of 360 K. Such short diffusion timescales suggest an efficient water recharge mechanism that could sustain the lunar surface water cycle. We estimate that the amount of water hosted by impact glass beads in lunar soils may reach up to 2.7 × 10¹⁴ kg. Our direct measurements of this surface reservoir of lunar water show that impact glass beads can store substantial quantities of solar wind-derived water on the Moon and suggest that impact glass may be water reservoirs on other airless bodies.

An exceedingly small number of high‐pressure polymorphs have been discovered in lunar samples. This situation does not seem to reconcile with the prolonged, intense bombardment of the lunar surface, which should produce suitable conditions for the formation of such polymorphs. Here we report the discovery of reidite, a high‐pressure polymorph of ZrSiO₄ with scheelite structure in lunar meteorite Sayh al Uhaymir (SaU) 169. The reidite occurs mainly as lamellae hosted within zircon, likely corresponding to a deviatoric‐dominated transformation. The presence of reidite in the regolith portion of SaU 169 indicates a narrow temperature and pressure path constrained by the phase stability under low pressure and suggests heterogeneous shock features in the porous lunar regolith where the ambient temperature increases much higher than that in compact rocks. The inventory of high‐pressure polymorphs might be restricted by such unusual cooling processes lunar samples experienced.

The visible and near‐infrared imaging spectrometer on board the Yutu‐2 rover of Chang'E‐4 mission has conducted 2 sets of spectrophotometric measurements at two sites on its 10^th lunar day. At each site, the reflectance spectra were measured on the same lunar regolith at different geometric configurations. The experiments reveal an increasing trend of the spectral reddening effect with the increasing phase angles, which may cause significant uncertainties on interpreting the maturity of the lunar regolith. Furthermore, the phase angles have significant effects on the 2‐μm band center and the 1‐μm band depth of the spectra, consequently on the estimation of mineral composition of the regolith. Finally, the derived average Hapke parameters using the in situ spectrophotometric measurements provide important ground‐truth for remote sensing observations.