Frozen in time: The electrochemical processes occurring in a battery are highly dynamic. To understand the complexities of the charge and discharge cycles, you need to be able to watch the processes in situ or to freeze the battery rapidly for ex situ analysis. Li et al. applied cryo–electron microscopy techniques commonly used for studying biological samples to examine batteries. They identified the solid electrolyte interphase that forms, observed the interactions of Li with the interphase, and captured the formation of dendrites that can be detrimental to the lifetime of a battery. Science , this issue p. 506
Flat perovskite crystals: Bulk crystals and thick films of inorganic-organic perovskite materials such as CH 3 NH 3 PbI 3 have shown promise as active material for solar cells. Dou et al. show that thin films—a single unit cell or a few unit cells thick—of a related composition, (C 4 H 9 NH 3 ) 2 PbBr 4 , form squares with edges several micrometers long. These materials exhibit strong and tunable blue photoluminescence. Science , this issue p. 1518
Highly efficient and selective electrochemical reduction of carbon dioxide represents one of the biggest scientific challenges in artificial photosynthesis, where carbon dioxide and water are converted into chemical fuels from solar energy. However, our fundamental understanding of the reaction is still limited and we do not have the capability to design an outstanding catalyst with great activity and selectivity a priori. Here we assemble uniform gold–copper bimetallic nanoparticles with different compositions into ordered monolayers, which serve as a well-defined platform to understand their fundamental catalytic activity in carbon dioxide reduction. We find that two important factors related to intermediate binding, the electronic effect and the geometric effect, dictate the activity of gold–copper bimetallic nanoparticles. These nanoparticle monolayers also show great mass activities, outperforming conventional carbon dioxide reduction catalysts. The insights gained through this study may serve as a foundation for designing better carbon dioxide electrochemical reduction catalysts.
16 July 2015 in Journal of the American Chemical Society