Glyoxal (CHOCHO) and formaldehyde (HCHO) trace gases were successfully retrieved from a multi-axis differential optical absorption spectroscopy (MAX-DOAS) system in Beijing (39.95°N, 116.32°E) and Baoding (39.15°N, 115.40°E), China. The measurements of these trace gases span the period from May 2017 to April 2018. Higher levels of trace gases were observed in Beijing most likely due to increased transport and industrial activities compared to Baoding. Different time scales were analyzed from seasonal to daily levels. Seasonal variation categorized by wintertime maximum and summertime minimum was observed for CHOCHO, while for HCHO maximum values were recorded during summer at both observation points. Variations in the diurnal cycle of trace gases were examined. The results are consistent with strong links to photo-oxidations of VOCs for HCHO production, whereas the CHOCHO diurnal variation can be related to anthropogenic effects in the evening. Weekends didn’t have any significant effect on both HCHO and CHOCHO. We investigated the temperature dependency of HCHO and CHOCHO. HCHO shows positive correlation with air temperature, which strengthened the argument that HCHO production is linked to photo-oxidation of VOCs. CHOCHO is anti-correlated with air temperature. This suggests that photolysis is a major sink for CHOCHO in Beijing and Baoding. We also investigated the relationship between CHOCHO and HCHO VCDs with enhanced vegetation index (EVI) data obtained from MODIS, which represents a direct relation with biogenic emissions. The positive correlations were observed among monthly mean HCHO VCDs and monthly mean EVI at both monitoring stations. The strong correlation of HCHO with EVI found, suggests that oxidation of isoprene and HCHO production is strongly related, while negative correlation was observed among CHOCHO VCDs and EVI.
24 September 2022 in Journal of Environmental Sciences
This study was aimed at presenting a continuous and spatially coherent picture of ammonia (NH3) distribution over the Indo-Gangetic Plain (IGP) by exploiting satellite observations. Atmospheric columns of ammonia were mapped over South Asia by using TES observations on board NASA’s Aura satellite. Monthly mean data were used to identify emission sources of atmospheric ammonia across the South Asian region. Data were analysed to explore temporal trends, seasonal cycles, and hot spots of atmospheric ammonia within the study area. The results show that the IGP region has the most ammonia concentrations in terms of column densities, and hence this region has been identified as an ammonia hot spot. This is attributed majorly to extensive agricultural activity. Time series showed a slight increase in ammonia column densities over the study area from 2004 to 2011. Different seasonal cycles were identified across the IGP region with maximum NH3 columns observed during the month of July in most of the subregions. Seasonality in an ammonia column is driven by different cropping patterns and meteorological conditions in the IGP subregions. Global emission inventories of atmospheric ammonia were largely overestimating as compared to satellite observations.
The emergence of the novel corona virus and the resulting lockdowns over various parts of the world have substantially impacted air quality due to reduced anthropogenic activity. The objective of this study is to investigate the impact of COVID-19 lockdown and Spring Festival on air quality of four major cities of Yangtze River Delta (YRD) region, including Shanghai, Nanjing, Hefei, and Hangzhou. In situ measurements were taken for nitrogen dioxide (NO2), particulate matter (PM2.5) and ozone (O3). In situ measurements from 1 January to 25 April were taken two years prior to COVID-19 (2018–19), during COVID-19 lockdown (2020), and one year after the COVID-19 (2021). The results indicated that the concentration of NO2 and PM2.5 dropped considerably during the lockdown days compared to normal days while the O3 concentration showed an upsurge. The NO2 showed reduction of about 54% on average during lockdown level 1 in 2020 whereas, PM 2.5 showed reduction of about 36% through the YRD. A substantial drop was observed in concentration of NO2 during the Spring Festival holidays throughout the YRD from 2019 to 2021.
Recently, the occurrence of fog and haze over China has increased. The retrieval of trace gases from the multi-axis differential optical absorption spectroscopy (MAX-DOAS) is challenging under these conditions. In this study, various reported retrieval settings for formaldehyde (HCHO) and sulfur dioxide (SO2) are compared to evaluate the performance of these settings under different meteorological conditions (clear day, haze, and fog). The dataset from 1st December 2019 to 31st March 2020 over Nanjing, China, is used in this study. The results indicated that for HCHO, the optimal settings were in the 324.5–359 nm wavelength window with a polynomial order of five. At these settings, the fitting and root mean squared (RMS) errors for column density were considerably improved for haze and fog conditions, and the differential slant column densities (DSCDs) showed more accurate values compared to the DSCDs between 336.5 and 359 nm. For SO2, the optimal settings for retrieval were found to be at 307–328 nm with a polynomial order of five. Here, root mean square (RMS) and fitting errors were significantly lower under all conditions. The observed HCHO and SO2 vertical column densities were significantly lower on fog days compared to clear days, reflecting a decreased chemical production of HCHO and aqueous phase oxidation of SO2 in fog droplets.