High-entropy alloys (HEAs) have attracted a great deal of interest over the last 14 years. One reason for this level of interest is related to these alloys breaking the alloying principles that have been applied for many centuries. Thus, HEAs usually possess a single phase (contrary to expectations according to the composition of the alloy) and exhibit a high level of performance in different properties related to many developing areas in industry. Despite this significant interest, most HEAs have been developed via ingot metallurgy. More recently, powder metallurgy (PM) has appeared as an interesting alternative for further developing this family of alloys to possibly widen the field of nanostructures in HEAs and improve some capabilities of these alloys. In this paper, PM methods applied to HEAs are reviewed, and some possible ways to develop the use of powders as raw materials are introduced.
Austenite formation during a continuous heating in a low carbon niobium microalloyed steel with a pearlite and ferrite initial microstructure has been studied. Characteristic transformation temperatures, Ac1, Acθ and Ac3 and the evolution of austenite formation have been determined by combining dilatometry and metallography in a range of heating rates from 0˙05 to 10 K s–1. It has been observed that nucleation and growth of austenite depends highly on the applied heating rate. At low heating rates (0˙05 K s–1) nucleation of austenite takes place both at pearlite nodules and at ferrite grain boundaries, while for higher heating rates (≥0˙5 K s–1), nucleation at grain boundaries is barely present compared to the nucleation at pearlite nodules. The heating rate also affects the austenite growth path and morphology and, thus, the distribution of martensite in the dual phase microstructure obtained at room temperature.