This study describes the potential conversion of dried microalgae. Chlorella vulgaris (C. vulgaris) into fatty acid methyl ester (FAME) using the direct transesterification (DT) method and using ionic liquids (ILs) as a catalyst. In this work, the performance of monocationic IL, namely 1-butyl-1-methylpyrrolidinium bromide (IL 1), and dicationic IL, namely 1,4-bis(1-methylpyrrolidinium-1-yl) butane dibromide (IL 2), as catalysts was compared for DT of C. vulgaris under microwave irradiation. The results revealed that IL 2 showed a better performance in catalyzing the DT reaction by producing 87.9 mg/g% of FAME, while the use of IL 1 led to 74.3 mg/g% of FAME under optimum conditions. The kinetic study for direct transesterification of C. vulgaris showed that the reaction followed a first order kinetic reaction where the activation energies were calculated to be 22.2499 kJ mol⁻¹ and 22.0413 kJ mol⁻¹ for IL 1 and IL 2, respectively.

This work presents an in-depth kinetic thermal degradation comparison between traditional monocationic and the newly developed dicationic ionic liquid (IL), both coupled with a bromide (Br⁻) anion by using non-isothermal thermogravimetric analysis. Thermal analyses of 1-butyl-1-methylpyrrolidinium bromide [C₄MPyr][Br] and 1,4-bis(1-methylpyrrolidinium-1-yl)butane dibromide [BisC₄MPyr][Br₂] were conducted at a temperature range of 50–650 °C and subjected to various heating rates, which are 5, 10, 15, 20 and 25 °C/min. Thermogravimetric analysis revealed that dicationic IL, [BisC₄MPyr][Br₂] is less thermally stable compared to monocationic [C₄MPyr][Br]. A detailed analysis of kinetic parameters, which are the activation energy (E_a) and pre-exponential factor (log A), was calculated by using Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO) and Starink. This study revealed that the average E_a and log A of [BisC₄MPyr][Br₂] are lower than [C₄MPyr][Br], which may be contributed to by its low thermal stability. Conclusively, it proved that the E_a and log A of ILs are strongly related to the thermal stability of ILs.