The current cloud thermodynamic phase discrimination by Cloud-Aerosol Lidar Pathfinder Satellite Observations (CALIPSO) is based on the depolarization of backscattered light measured by its lidar [Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP)]. It assumes that backscattered light from ice crystals is depolarizing, whereas water clouds, being spherical, result in minimal depolarization. However, because of the relationship between the CALIOP field of view (FOV) and the large distance between the satellite and clouds and because of the frequent presence of oriented ice crystals, there is often a weak correlation between measured depolarization and phase, which thereby creates significant uncertainties in the current CALIOP phase retrieval. For water clouds, the CALIOP-measured depolarization can be large because of multiple scattering, whereas horizontally oriented ice particles depolarize only weakly and behave similarly to water clouds. Because of the nonunique depolarization–cloud phase relationship, more constraints are necessary to uniquely determine cloud phase. Based on theoretical and modeling studies, an improved cloud phase determination algorithm has been developed. Instead of depending primarily on layer-integrated depolarization ratios, this algorithm differentiates cloud phases by using the spatial correlation of layer-integrated attenuated backscatter and layer-integrated particulate depolarization ratio. This approach includes a two-step process: 1) use of a simple two-dimensional threshold method to provide a preliminary identification of ice clouds containing randomly oriented particles, ice clouds with horizontally oriented particles, and possible water clouds and 2) application of a spatial coherence analysis technique to separate water clouds from ice clouds containing horizontally oriented ice particles. Other information, such as temperature, color ratio, and vertical variation of depolarization ratio, is also considered. The algorithm works well for both the 0.3° and 3° off-nadir lidar pointing geometry. When the lidar is pointed at 0.3° off nadir, half of the opaque ice clouds and about one-third of all ice clouds have a significant lidar backscatter contribution from specular reflections from horizontally oriented particles. At 3° off nadir, the lidar backscatter signals for roughly 30% of opaque ice clouds and 20% of all observed ice clouds are contaminated by horizontally oriented crystals.

Analytic equations are developed for the single-scattering properties of a spherical particle embedded in an absorbing medium, which include absorption, scattering, extinction efficiencies, the scattering phase function, and the asymmetry factor. We derive absorption and scattering efficiencies by using the near field at the surface of the particle, which avoids difficulty in obtaining the extinction based on the optical theorem when the far field is used. Computational results demonstrate that an absorbing medium significantly affects the scattering of light by a sphere.

An accurate parameterization is presented for the infrared radiative properties of cirrus clouds. For the single-scattering calculations, a composite scheme is developed for randomly oriented hexagonal ice crystals by comparing results from Mie theory, anomalous diffraction theory (ADT), the geometric optics method (GOM), and the finite-difference time domain technique. This scheme employs a linear combination of single-scattering properties from the Mie theory, ADT, and GOM, which is accurate for a wide range of size parameters. Following the approach of Q. Fu, the extinction coefficient, absorption coefficient, and asymmetry factor are parameterized as functions of the cloud ice water content and generalized effective size (Dge). The present parameterization of the single-scattering properties of cirrus clouds is validated by examining the bulk radiative properties for a wide range of atmospheric conditions. Compared with reference results, the typical relative error in emissivity due to the pa... Abstract An accurate parameterization is presented for the infrared radiative properties of cirrus clouds. For the single-scattering calculations, a composite scheme is developed for randomly oriented hexagonal ice crystals by comparing results from Mie theory, anomalous diffraction theory (ADT), the geometric optics method (GOM), and the finite-difference time domain technique. This scheme employs a linear combination of single-scattering properties from the Mie theory, ADT, and GOM, which is accurate for a wide range of size parameters. Following the approach of Q. Fu, the extinction coefficient, absorption coefficient, and asymmetry factor are parameterized as functions of the cloud ice water content and generalized effective size (Dge). The present parameterization of the single-scattering properties of cirrus clouds is validated by examining the bulk radiative properties for a wide range of atmospheric conditions. Compared with reference results, the typical relative error in emissivity due to the pa...

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission will provide a calibration laboratory in orbit for the purpose of accurately measuring and attributing climate change. CLARREO measurements establish new climate change benchmarks with high absolute radiometric accuracy and high statistical confidence across a wide range of essential climate variables. CLARREO's inherently high absolute accuracy will be verified and traceable on orbit to Système Internationale (SI) units. The benchmarks established by CLARREO will be critical for assessing changes in the Earth system and climate model predictive capabilities for decades into the future as society works to meet the challenge of optimizing strategies for mitigating and adapting to climate change. The CLARREO benchmarks are derived from measurements of the Earth's thermal infrared spectrum (5–50 μm), the spectrum of solar radiation reflected by the Earth and its atmosphere (320–2300 nm), and radio occultation refractivity from which accurate temperature profiles are derived. The mission has the ability to provide new spectral fingerprints of climate change, as well as to provide the first orbiting radiometer with accuracy sufficient to serve as the reference transfer standard for other space sensors, in essence serving as a “NIST [National Institute of Standards and Technology] in orbit.” CLARREO will greatly improve the accuracy and relevance of a wide range of space-borne instruments for decadal climate change. Finally, CLARREO has developed new metrics and methods for determining the accuracy requirements of climate observations for a wide range of climate variables and uncertainty sources. These methods should be useful for improving our understanding of observing requirements for most climate change observations.

A three-dimensional finite-difference time-domain (FDTD) program has been developed to provide a numerical solution for light scattering by nonspherical dielectric particles. The perfectly matched layer (PML) absorbing boundary condition (ABC) is used to truncate the computational domain. As a result of using the PML ABC, the present FDTD program requires much less computer memory and CPU time than those that use traditional truncation techniques. For spheres with particle-size parameters as large as 40, the extinction and absorption efficiencies from the present FDTD program match the Mie results closely, with differences of less than ∼1%. The difference in the scattering phase function is typically smaller than ∼5%. The FDTD program has also been checked by use of the exact solution for light scattering by a pair of spheres in contact. Finally, applications of the PML FDTD to hexagonal particles and to spheres aggregated into tetrahedral structures are presented.