It has been reported that iron tailing powder (ITP) has the potential to partially replace cement to prepare ultra-high-performance concrete (UHPC). However, the reactivity of ITP particles in concrete largely depends on the curing method. This study investigates the effects of curing conditions on the mechanical and microstructural properties of UHPC containing ITP. To achieve this objective, three research tasks are conducted, including (1) preparing seven concrete formulations by introducing ITP; (2) characterizing their mechanical performance under different curing regimes; and (3) analyzing their microstructure by XRD patterns, FTIR analysis, and SEM observation. The experimental results show that there is an optimum ITP dosage (15%) for their application. The concrete with 15% ITP under standard curing obtains 94.3 MPa at 7 days, their early-age strength could be even further increased by ~30% (warm-water curing) and ~35% (steamed curing). The steam curing regime stimulates the activity of ITP and refines the microstructure. This study demonstrates the potential of replacing Portland cement with ITP in UHPC production.
This laboratory study explores a cost-effective and environmental friendly foamed paste with satisfactory physical properties and outstanding thermal insulation properties. Such a composite material was made by using a high volume of class F coal fly ash as a replacement of Portland cement (70% by mass) and nano-montmorillonite as an admixture. Replacing cement with fly ash at high levels is environmentally and economically desirable, as this not only reduces the energy and carbon footprint of the foamed paste, but also diverts the coal fly ash from the waste stream. A statistical design of experiments was adopted and executed to investigate the effects of various factors on the properties of the composite. At the age of 28 days, the pastes exhibited a high compressive strength ranging from 1.77 MPa to 6.51 MPa and a low thermal conductivity in the range of 0.071 W (m−1 K−1) to 0.173 W (m−1 K−1). Two foamed mixes were chosen for further investigation as they presented the best and worst performance as a thermal insulation material. The scanning electron microscopy shed light on the best foamed mix, which contains 70% fly ash, 30% cement, and 1% nano-montmorillonite, and how its microstructure differed from that of the worst mix without nano-montmorillonite. The Ca content, Si/Ca ratio and Al/Ca ratio were obtained from energy-dispersive X-ray spectroscopy of hardened samples, and used to help explain the observed strength difference between these two mixes. X-ray diffraction was also employed to elucidate the hydration mechanism of HVFC foamed paste.
In cold climate regions, the energy associated with indoor heating constitutes a large portion of energy consumption. Increasing energy utilization efficiency is critically important for both economic and environmental reasons. Directly converting electrical energy to thermal energy using joule heating construction elements can save energy and investment to the water pipelines which have been extensively used for indoor heating in China. The fired brick has been extensively used to make pavements, walls and other masonry. Taking advantage of the high dispersion quality of graphene oxide (GO) in water, as well as the firing process used to make fired bricks, graphene nanocomposite bricks with excellent electrical properties and improved mechanical performance were prepared in China. The compressive strength of the bricks showed a substantial increase from 3.15 MPa to 7.21 MPa when GO concentration was 0.1 wt.%. Through applying 5 volts of electrical field within 5 minutes, the nanocomposites can be heated from room temperature to 60 °C, 110 °C and 160 °C for the nanocomposite bricks with graphene concentration of 3 wt.%, 4 wt.% and 5 wt.%, respectively, due to the extremely low percolation threshold (~0.5 wt.%) and high conductivity (10 Ω·cm at 1 wt.%). The sheets were connected more tightly when the GO content was increased. The thermal efficiency can reach up to 88% based on the applied voltage, measured resistance and temperature rise curves.
The use of ice control chemicals has become a crucial tool in providing a reasonable level of service on wintery roadways. Yet, there is little research on how the durability of concrete decks in cold climate might be affected by their exposure to deicers. This work presents a streamlined method of developing exposure maps that can be used to better understand the potential effects that deicer usage and other relevant variables may have on an agency's concrete infrastructure. Using the Oregon Department of Transportation (ODOT) as a case study, this work started with a survey of two relevant stakeholder groups, followed by the collection of relevant data for developing exposure maps for 12 selected representative ODOT concrete bridge decks. Some issues with data availability and quality were identified. It is recommended that deicer type and application rates, traffic volume, climatic conditions, and concrete mix design and rehabilitation data should be documented into an integrated deck preservation program, or be added to the existing bridge management systems. The inventory of such data would ultimately enable the agency to examine the role of various factors in the premature deterioration of its concrete bridge decks.