The energy market is facing a major transition, in which natural gas and renewable gasses will play an important role. However, changing gas sources and compositions will force the gas transporters, gas engine manufacturers, and gas grid operators to monitor the gas quality in a more intensive way. This leads to the need for lower cost, smaller, and easy to install gas quality sensors. A new approach is proposed in this study that is based on the chemical interactions of the various gas components and responsive layers applied to an array of capacitive interdigitated electrodes. For Liquid Natural Gas (LNG), containing a relative high concentration of higher hydrocarbons, an array of ten capacitive chips is proposed, that is sufficient to calculate the full composition, and can be used to calculate energy parameters, such as Wobbe Index, Calorific Value, and Methane Number. A first prototype was realized that was small enough to be inserted in low and medium pressure gas pipes and LNG engine fuel lines. Adding the pressure and temperature data to the chip readings enables the determination of the concentrations of the various alkanes, hydrogen, nitrogen, and carbon dioxide, including small fluctuations in water vapor pressure. The sensitivity and selectivity of the new sensor is compared to a compact analyzer employing tunable filter infrared spectrometry.
19 April 2023 in IEEE Journal of Selected Topics in Applied Earth Observations and Remote Sensing
The goal of hyperspectral image analysis is often to determine which materials, out of a given set of possibilities, are present in each pixel. As hyperspectral data is being gathered in rapidly increasing amounts, automatic image analysis is becoming progressively more important. Automatic identification of materials from a mixed pixel is possible with 1) Bayesian unmixing algorithms, and 2) multiobjective sparse unmixing algorithms when a method such as elbow estimation is used to select the best solution from the set of Pareto-optimal solutions. We have developed a new elbow estimation method called termination condition adaptive elbow (TCAE) for selecting the best solution from the set of Pareto-optimal solutions to a bi-objective unmixing problem. Specifically, the two objectives are assumed to be the sparsity level of the fractional abundance vector and the reconstruction error. We conducted experiments with real-world unmixing applications in mind, and TCAE performed significantly better than a state-of-the-art elbow estimation method when they were both used to select the best solution from the sequence of fractional abundance vectors generated by iterative spectral mixture analysis (ISMA). Furthermore, the combination of ISMA and TCAE was able to identify endmembers from mixed pixels several times faster and with higher F 1 -score than the two Bayesian unmixing algorithms used as a reference. We conclude that the combination of ISMA and TCAE facilitates automatic, reliable and rapid identification of endmembers from mixed pixels.