Nanofertilizers are increasingly explored for sustainable micronutrient delivery in agriculture. Pre-treating seeds with nanofertilizers prior to planting (i.e., seed priming) reduces concerns about nanoparticle (NP) fertilizer non-target dispersion; however, priming formulations and concentrations must be carefully selected to avoid germination inhibition and toxicity. Here we investigate changes in corn seed germination and seedling development after seed priming with ZnO NPs, ZnO bulk and ZnCl₂. To evaluate the effects sterile seeds were immersed in priming solutions of 0, 20, 40, 80, 160 mg L⁻¹ Zn for the three Zn sources. Following an 8 h priming the seeds were evaluated for germination and vigor for 5 days on germination paper. Root and shoot lengths were measured as well as fresh and dry biomass. Compared to the control, the ZnO NP and ZnCl₂ seed priming promoted beneficial effects. ZnO NP seed-priming exhibited a concentration dependent profile in improving seedling growth, with greatest benefit around 80 mg L⁻¹, providing 17%, 25% and 12% higher values than control for germination, root length, and dry biomass production, respectively. In contrast, seeds primed with bulk ZnO did not differ from the control. These findings support NP-seed priming as an alternative to delivery of essential micronutrients, such as zinc, to corn seedlings.

Oxisols ( Latossolos ) are widely distributed in tropical zones and generally characterized by high levels of surface and subsurface acidity. In Brazil, most Oxisols are managed under no-till conditions with surface application of acidity amendments. This study aimed to evaluate lime application strategies (incorporated and surface) for achieving the desired soil base saturation (BS%) levels (44, 60, 70, and 90 %) and the effect of phosphogypsum + lime application on soil chemical properties as well as wheat and [...] ABSTRACT Oxisols ( Latossolos ) are widely distributed in tropical zones and generally characterized by high levels of surface and subsurface acidity. In Brazil, most Oxisols are managed under no-till conditions with surface application of acidity amendments. This study aimed to evaluate lime application strategies (incorporated and surface) for achieving the desired soil base saturation (BS%) levels (44, 60, 70, and 90 %) and the effect of phosphogypsum + lime application on soil chemical properties as well as wheat and

This research evaluates the synthesis and characterization of nanometric-sized metallic particles with potential application as support materials for supplying nutrients to plants. Nanoscale Zn, Mn, Fe, and Cu oxides particles were synthesized using microwave-assisted synthesis. Nanoparticles (NPs) were characterized with Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), specific surface area (SSA), and total chemical analysis. Synthesized NPs were all in oxide forms and characterized for confirmation of size, shape, surface structure, crystalline nature, and study of elemental proportion. The results indicate that synthesized NPs size was ranged between 20 and 50nm and was all in their respective oxide forms as ZnO, Mn₃O₄, Fe₃O₄, and CuO.

Fertilizer formulation alternatives that avoid unnecessary losses and environmental impacts are being investigated in agricultural management. Seed priming with nanofertilizers prior to planting, reduces concerns about non-target dispersion; however, priming formulations and concentrations must be carefully selected to avoid undesired effects. Here, seed germination and seedling development were evaluated after seed priming with CuO nanoparticles (NPs), CuO bulk and CuCl2. The seeds were immersed in priming solutions of 0, 20, 40, 80 and 160 mg.L−1 Cu for the three Cu sources. Following 8 hours priming, the seeds were evaluated for germination and vigor (first germination count). Root and shoot lengths were measured as well as shoot and root dry biomass. The copper NP did not show any toxic effects on corn seed germination and growth, and also promoted higher biomass when compared to the other Cu sources. On the other hand, CuCl2 primed seeds exhibited Cu-toxicity in roots and shoots for all concentrations tested. Bulk Cu priming results indicated the better role of NPs size effects. These findings support NP-seed priming as an alternative to delivery of essential micronutrients, such as copper, to corn seedlings.

Nutrient leaf application is complementary to soybean nutritional management, mainly at maturity, when plants present high nutritional demand and high nutrients and photoassimilate translocation rates for seed production. The aim of this research was to evaluate the agronomic performance, physiological quality, and nutritional contents of soybean seeds after application of different rates (0, 0.50, 1.0, 1.5, 2.0, and 2.5 kg ha⁻¹) of foliar fertiliser containing calcium (20%) and boron (4%) at the R3 stage (onset of pod formation). This research was carried out in two sites (Guaragi and Floresta) both in Parana State, Brazil, in randomised complete blocks with 4 replicates. Calcium and boron leaf application increased grain sulphur and nitrogen levels (Guaragi) but reduced phosphorus and magnesium (Floresta). Regarding physiological quality, foliar fertilisation increased the index of germination speed. The yield and number of pods increased up to the rate of 0.6 and 1.2 kg ha⁻¹ of leaf fertiliser in Floresta. Foliar fertilisation with calcium and boron showed advantages, however, results depended on the site, indicating different levels of soil fertility and climatic characteristics.

In no-till (NT), liming and urea fertilization are performed on the soil surface, which can increase nitrogen (N) losses via ammonia volatilization. On the basis of N fertilization management, gypsum application provides a promising alternative for improving N uptake by plants. Therefore, the objective of this study was to evaluate the N behavior loss by NH3-N volatilization, the soil pH at a depth of 0 – 0.05 m, leaf N content, and N uptake by second-season corn after lime and gypsum application in a Rhodic Ferralsol under NT. Overall, the treatments consisted of a 4 × 4 factorial arrangement with four lime rates (0, 2.6, 5.4, and 8.1 Mg ha-1) and four gypsum rates (0, 4, 8, and 12 Mg ha-1). During the study period, second-season corn was cultivated for two years and fertilized with urea, for which the N losses through ammonia volatilization, soil pH, leaf N content, and N uptake values were quantified. The losses through ammonia volatilization were subjected to nonlinear regression using a logistic model, and the other variables were subjected to linear regressions. The lime applied by broadcasting on the soil surface in the NT increased the pH of the topsoil and increased N losses via NH3-N volatilization in the second-season corn. Further, the N losses in the NT treated with lime accounted for 58% of the applied N, which increased by 2.3 to 2.5% for each Mg ha-1 of lime applied. Therefore, lime or gypsum application did not improve the status of N in second-season corn in soils with low acidity and no S deficiency.