Tungsten oxide nanostructures were modified by oxygen vacancies through hydrothermal treatment. Both the crystalline structure and morphological appearance were completely changed. Spherical WO₃·H₂O was prepared from tungstic acid solution by aging at room temperature, while rod-like WO₃·0.33H₂O was prepared by hydrothermal treatment of tungstic acid solution at 120 °C. These structures embedded in sodium alginate (SA)/polyvinylpyrrolidone (PVP) were synthesized as novel porous beads by gelation method into calcium chloride solution. The performance of the prepared materials as photocatalysts is examined for methylene blue (MB) degradation in aqueous solutions. Different operation parameters affecting the dye degradation process, such as light intensity, illumination time, and photocatalyst dosage are investigated. Results revealed that the photocatalytic activity of novel nanocomposite changed with the change in WO₃ morphology. Namely, the beads with rod nanostructure of WO₃ have shown better effectiveness in MB removal than the beads containing WO₃ in spherical form. The maximum degradation efficiency was found to be 98% for WO₃ nanorods structure embedded beads, while the maximum removal of WO₃ nanospheres structure embedded beads was 91%. The cycling-ability and reuse results recommend both prepared structures to be used as effective tools for treating MB dye-contaminated wastewaters. The results show that the novel SA/PVP/WO₃ nanocomposite beads are eco-friendly nanocomposite materials that can be applied as photocatalysts for the degradation of cationic dyes in contaminated water.

A direct borohydride fuel cell (DBFC) is a type of low temperature fuel cell which requires efficient and low cost proton exchange membranes in order to commercialize it. Herein, a binary polymer blend was formulated from inexpensive and ecofriendly polymers, namely polyethylene oxide (PEO) and poly vinyl alcohol (PVA). Phosphated titanium oxide nanotube (PO₄TiO₂) was synthesized from a simple impregnation–calcination method and later embedded for the first time as a doping agent into this polymeric matrix with a percentage of 1–3 wt%. The membranes’ physicochemical properties such as oxidative stability and tensile strength were enhanced with increasing doping addition, while the borohydride permeability, water uptake, and swelling ratio of the membranes decreased with increasing PO₄TiO₂ weight percentage. However, the ionic conductivity and power density increased to 28 mS cm⁻¹ and 72 mWcm⁻² respectively for the membrane with 3 wt% of PO₄TiO₂ which achieved approximately 99% oxidative stability and 40.3 MPa tensile strength, better than Nafion117 (92% RW and 25 MPa). The fabricated membrane with the optimum properties (PVA/PEO/PO₄TiO₂-3) achieved higher selectivity than Nafion117 and could be efficient as a proton exchange membrane in the development of green and low cost DBFCs.

The presence of pharmaceutical residues in aquatic environments represents a risk for the equilibrium of the ecosystem and may seriously affect human safety itself in the long term. To address this issue, we have synthesized functional materials based on highly-reduced graphene oxide (HRGO), sulfonated graphene (SG), and magnetic sulfonated graphene (MSG). The method of synthesis adopted is simple and inexpensive and makes use of plastic bottle waste as the raw material. We have tested the fabricated materials for their adsorption efficiency against two model antibiotics in aqueous solutions, namely Garamycin and Ampicillin. Our tests involved the optimization of different experimental parameters of the adsorption process, such as starting antibiotic concentration, amount of adsorbent, and time. Finally, we characterized the effect of the antibiotic adsorption process on common living organisms, namely Escherichia coli DH5α (E. coli DH5α) bacteria. The results obtained demonstrate the efficiency of the method in addressing the issue of the emergence of antibiotic-resistant bacteria, which will help in preventing changes in the ecosystem.

The combination of adsorption and photodegradation processes is an effective technique for the removal of dye contaminants from water, which is motivating the development of novel adsorbent-photocatalyst materials for wastewater treatment. Herein, novel nanocomposite porous beads were developed using titanium dioxide (TiO₂) nanotubes embedded in a sodium alginate (SA)/polyvinylpyrrolidone (PVP) matrix using calcium chloride solution as a crosslinker. The prepared nanocomposite beads’ performance was examined as an adsorbent-photocatalyst for the breakdown of methylene blue in aqueous solutions. Several operation factors influencing the dye decomposition process, including photocatalyst dosage, illumination time, light intensity, and stability were investigated. The findings demonstrated that the removal activity of the beads changed with the TiO₂ weight ratio in the composite. It was found that SA/PVP/TiO₂-3 nanocomposite beads presented the greatest deterioration efficiency for methylene blue dye (98.9%). The cycling ability and reusability of the prepared SA/PVP/TiO₂ nanocomposite beads recommend their use as efficient, eco-friendly materials for the treatment of wastewaters contaminated with cationic dyes.