We have studied the electronic structure of the nonmagnetic LiFeAs (Tc$\sim${}18\,\,K) superconductor using angle-resolved photoemission spectroscopy. We find a notable absence of the Fermi surface nesting, strong renormalization of the conduction bands by a factor of 3, high density of states at the Fermi level caused by a van Hove singularity, and no evidence for either a static or a fluctuating order except superconductivity with in-plane isotropic energy gaps. Our observations suggest that these electronic properties capture the majority of ingredients necessary for the superconductivity in iron pnictides.
Elucidating the nature of the magnetism of a high-temperature superconductor is crucial for establishing its pairing mechanism. The parent compounds of the cuprate and iron-pnictide superconductors exhibit Néel and stripe magnetic order, respectively. However, FeSe, the structurally simplest iron-based superconductor, shows nematic order (Ts=90 K), but not magnetic order in the parent phase, and its magnetic ground state is intensely debated. Here we report inelastic neutron-scattering experiments that reveal both stripe and Néel spin fluctuations over a wide energy range at 110 K. On entering the nematic phase, a substantial amount of spectral weight is transferred from the Néel to the stripe spin fluctuations. Moreover, the total fluctuating magnetic moment of FeSe is ∼60% larger than that in the iron pnictide BaFe2As2. Our results suggest that FeSe is a novel S=1 nematic quantum-disordered paramagnet interpolating between the Néel and stripe magnetic instabilities.
The electronic structure of the iron chalcogenide superconductor was investigated by high-resolution angle-resolved photoemission spectroscopy (ARPES). The results were compared to DFT calculations showing some significant differences between the experimental electronic structure of , DFT calculations, and existing data on . The bands undergo a pronounced orbital-dependent renormalization, different from what was observed for and any other pnictides.
Neutron diffraction and bulk measurements are used to determine the nature of the low-temperature ordered state in , a spin-chain compound with competing interactions. The spin structure is found to be helimagnetic, with a propagation vector , . The nearest-neighbor exchange constant and frustration ratio are estimated to be and , respectively. For idealized quantum spin chains, these parameter values would signify a gapped spin-liquid ground state with commensurate spin correlations. The observed temperature dependence of the magnetic propagation vector in is attributed to a competition between incommensurate helimagnetism in the classical spin model and commensurability in the quantum case. It is also proposed that long-range ordering in is facilitated by intrinsic nonstoichiometry.
1 September 2013 in Journal of Colloid and Interface Science