We studied the shear bond strength (SBS) of two PEEK composites (BioHPP, BioHPP plus) with three veneering composites: Visio.lign, SR Nexco and VITA VM LC, depending on the surface treatment: untreated, sandblasted with 110 μm Al₂O₃, sandblasted and cleaned ultrasonically in 80% ethanol, with or without adhesive Visio.link, with applied Visio.link and MKZ primer. For the BioHPP plus, differential scanning calorimetry (DSC) revealed a slightly lower glass transition temperature (T_g 150.4 ± 0.4 °C) and higher melting temperature (T_m 339.4 ± 0.6 °C) than those of BioHPP (T_g 151.3 ± 1.3 °C, T_m 338.7 ± 0.2 °C). The dynamical mechanical analysis (DMA) revealed a slightly higher storage modulus of BioHPP (E’ 4.258 ± 0.093 GPa) than of BioHPP plus (E′ 4.193 ± 0.09 GPa). The roughness was the highest for the untreated BioHPP plus, and the lowest for the polished BioHPP. The highest hydrophobicity was achieved on the sandblasted BioHPP plus, whereas the highest hydrophilicity was found on the untreated BioHPP. The highest SBSs were determined for BioHPP and Visio.lign, adhesive Visio.link (26.31 ± 4.17 MPa) or MKZ primer (25.59 ± 3.17 MPa), with VITA VM LC, MKZ primer and Visio.link (25.51 ± 1.94 MPa), and ultrasonically cleaned, with Visio.link (26.28 ± 2.94 MPa). For BioHPP plus, the highest SBS was determined for a sandblasted surface, cleaned ultrasonically, with the SR Nexco and Visio.link (23.39 ± 2.80 MPa).

The surface properties of wood fiber (WF) filled polymer composites depend on the filler loading and are closely related to the distribution and orientation in the polymer matrix. In this study, wood fibers (WF) were incorporated into thermoplastic composites based on non-recycled polypropylene (PP) and recycled (R-PP) composites by melt compounding and injection moulding. ATR-FTIR (attenuated total reflection Fourier transform infrared spectroscopy) measurements clearly showed the propagation of WF functional groups at the surface layer of WF-PP/WF-R-PP composites preferentially with WF loading up to 30%. Optical microscopy and nanoindentation method confirmed the alignment of thinner skin layer of WF-PP/WF-R-PP composites with increasing WF addition. The thickness of the skin layer was mainly influenced by the WF loading. The effect of the addition of WF on modulus and hardness, at least at 30 and 40 wt.%, varies for PP and R-PP matrix. On the other hand, surface zeta potential measurements show increased hydrophilicity with increasing amounts of WF. Moreover, WF in PP/R-PP matrix is also responsible for the antioxidant properties of these composites as measured by DPPH (2,2′-diphenyl-1-picrylhydrazyl) assay.

A new silver-based alloy with 2 wt.% of lanthanum (La) was studied as a potential candidate for electric contact material. The alloy was prepared by rapid solidification, performed by the melt spinning technique. Microstructural examination of the rapidly solidified ribbons revealed very fine grains of α_Ag and intermetallic Ag₅La particles, which appear in the volume of the grains, as well as on the grain boundaries. Rapid solidification enabled high microstructural refinement and provided a suitable starting microstructure for the subsequent internal oxidation, resulting in fine submicron-sized La₂O₃ oxide nanoparticle formation throughout the volume of the silver matrix (α_Ag). The resulting nanostructured Ag-La₂O₃ microstructure was characterised by high-resolution FESEM and STEM, both equipped with EDX. High-temperature internal oxidation of the rapidly solidified ribbons essentially changed the microstructure. Mostly homogeneously dispersed nano-sized La₂O₃ were formed within the grains, as well as on the grain boundaries. Three mechanisms of internal oxidation were identified: (i) the oxidation of La from the solid solution; (ii) partial dissolution of finer Ag₅La particles before the internal oxidation front and oxidation of La from the solid solution; and (iii) direct oxidation of coarser Ag₅La intermetallic particles.

The tendencies of development within the field of engineering materials show a persistent trend towards the increase of strength and toughness. This pressure is particularly pronounced in the field of steels, since they compete with light alloys and composite materials in many applications. The improvement of steels’ mechanical properties is sought to be achieved with the formation of exceptionally fine microstructures ranging well into the nanoscale, which enable a substantial increase in strength without being detrimental to toughness. The preferred route by which such a structure can be produced is not by applying the external plastic deformation, but by controlling the phase transformation from austenite into ferrite at low temperatures. The formation of bainite in steels at temperatures lower than about 200 °C enables the obtainment of the bulk nanostructured materials purely by heat treatment. This offers the advantages of high productivity, as well as few constraints in regard to the shape and size of the workpiece when compared with other methods for the production of nanostructured metals. The development of novel bainitic steels was based on high Si or high Al alloys. These groups of steels distinguish a very fine microstructure, comprised predominantly of bainitic ferrite plates, and a small fraction of retained austenite, as well as carbides. The very fine structure, within which the thickness of individual bainitic ferrite plates can be as thin as 5 nm, is obtained purely by quenching and natural ageing, without the use of isothermal transformation, which is characteristic for most bainitic steels. By virtue of their fine structure and low retained austenite content, this group of steels can develop a very high hardness of up to 65 HRC, while retaining a considerable level of impact toughness. The mechanical properties were evaluated by hardness measurements, impact testing of notched and unnotched specimens, as well as compression and tensile tests. Additionally, the steels’ microstructures were characterised using light microscopy, field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM). The obtained results confirmed that the strong refinement of the microstructural elements in the steels results in a combination of extremely high strength and very good toughness.

A novel high C high Si carbide free bainitic steel was developed for the production of cold work tools, knives, and rolls, requiring high hardness, toughness, as well as abrasive/adhesive wear resistance and resistance to galling at low costs. The steel was tribologically tested in dry sliding conditions under abrasive and adhesive wear mode, facilitated by using alumina and bearing steel ball as a counter-material, respectively. It was determined that carbide dissolution occurs under high contact pressures, thereby enriching the surrounding matrix with carbon and locally increasing the retained austenite content. The high retained austenite at the sliding interface increases the steels work hardening capacity and promotes superior wear resistance when compared to much more alloyed cold work tool steel, such as AISI D2. The steel has a high resistance to galling as determined by sliding against a soft steel bar due to its chemical composition.