Passive vapor generation systems with interfacial solar heat localization enable high-efficiency low-cost desalination. In particular, recent progress combining interfacial solar heating and vaporization enthalpy recycling through a capillary-fed multistage architecture, known as the thermally-localized multistage solar still (TMSS), significantly improves the performance of passive solar desalination. Yet, state-of-the-art experimental demonstrations of solar-to-vapor conversion efficiency are still limited since the dominant factors and the general design principle for TMSS were not well-understood. In this work, we show optimizing the overall heat and mass transport in a multistage configuration plays a key role for further improving the performance. This understanding also increases the flexibility of material choices for the TMSS design. Using a low-cost and free-of-salt accumulation TMSS architecture, we experimentally demonstrated a record-high solar-to-vapor conversion efficiency of 385% with a production rate of 5.78 L m⁻² h⁻¹ under one-sun illumination, where more than 75% of the total production was collected through condensation. This work not only significantly improves the performance of existing passive solar desalination technologies for portable and affordable drinking water, but also provides a comprehensive physical understanding and optimization principle for TMSS systems.

This review summarizes recent advances in passive thermally-localized solar desalination and provides a roadmap for more efficient, reliable, and commercially feasible solar desalination technologies.

Passive solar membrane distillation (MD) is an emerging technology to alleviate water scarcity. Recently, its performance has been enhanced by multistage design, though the gains are marginal due to constrained temperature and vapor pressure gradients across the device. This makes condenser cooling enhancement a questionable choice. We argue that condenser heating could suppress the marginal effect of multistage solar MD by unlocking the moisture transport limit in all distillation stages. Here, we propose a stage temperature boosting (STB) concept that directs low-temperature heat to the condensers in the last stages, enhancing moisture transport across all stages. Through STB in the last two stages with a heat flux of 250 W m⁻², a stage-averaged distillation flux of 1.13 L m⁻² h⁻¹ S⁻¹ was demonstrated using an 8-stage MD device under one-sun illumination. This represents an 88% enhancement over the state-of-the-art 10-stage solar MD devices. More notably, our analysis indicates that 16-stage STB-MD devices driven by solar energy and waste heat can effectively compete with existing photovoltaic reverse osmosis (PV-RO) systems, potentially elevating freshwater production with low-temperature heat sources.

Solar evaporation with solute replacement enables the evaporation of a variety of source solutions towards real-world applications, via the decoupling of heat and mass transport pathways.