With and now without: Perfluoro‐tagged catalysts immobilized on fluorous reversed‐phase silica gel can be used for Suzuki and Sonogashira C–C coupling reactions (see scheme; R¹=e.g., phenyl, 4‐MeOC₆H₄, R²=e.g., 4‐NO₂C₆H₄, 4‐MeCOC₆H₄, X=Br, I) without the need for perfluorinated solvents. After the reaction the products were isolated by decantation and the Pd catalysts were recovered and reused.