Single-photon–added coherent states are the result of the most elementary amplification process of classical light fields by a single quantum of excitation. Being intermediate between a single-photon Fock state (fully quantum-mechanical) and a coherent (classical) one, these states offer the opportunity to closely follow the smooth transition between the particle-like and the wavelike behavior of light. We report the experimental generation of single-photon–added coherent states and their complete characterization by quantum tomography. Besides visualizing the evolution of the quantum-to-classical transition, these states allow one to witness the gradual change from the spontaneous to the stimulated regimes of light emission.

The possibility of arbitrarily “adding” and “subtracting” single photons to and from a light field may give access to a complete engineering of quantum states and to fundamental quantum phenomena. We experimentally implemented simple alternated sequences of photon creation and annihilation on a thermal field and used quantum tomography to verify the peculiar character of the resulting light states. In particular, as the final states depend on the order in which the two actions are performed, we directly observed the noncommutativity of the creation and annihilation operators, one of the cardinal concepts of quantum mechanics, at the basis of the quantum behavior of light. These results represent a step toward the full quantum control of a field and may provide new resources for quantum information protocols.

We report the experimental realization and tomographic analysis of quantum light states obtained by exciting a classical thermal field by a single photon. Such states, although completely incoherent, possess a tunable degree of quantumness which is here exploited to put to a stringent experimental test some of the criteria proposed for the proof and the measurement of state nonclassicality. The quantum character of the states is also given in quantum information terms by evaluating the amount of entanglement that they can produce.

Conventional spectroscopy uses classical light to detect matter properties through the variation of its response with frequencies or time delays. Quantum light opens up new avenues for spectroscopy by utilizing parameters of the quantum state of light as novel control knobs and through the variation of photon statistics by coupling to matter. This Roadmap article focuses on using quantum light as a powerful sensing and spectroscopic tool to reveal novel information about complex molecules that is not accessible by classical light. It aims at bridging the quantum optics and spectroscopy communities which normally have opposite goals: manipulating complex light states with simple matter e.g. qubits versus studying complex molecules with simple classical light, respectively. Articles cover advances in the generation and manipulation of state-of-the-art quantum light sources along with applications to sensing, spectroscopy, imaging and interferometry.