Molybdenum disulfide (MoS2) has been recognized as one of the most promising catalysts to replace Pt for hydrogen evolution reaction (HER) electrocatalysis because of the elemental abundance, excellent catalytic potential, and stability. However, its HER efficiency is still below that of Pt. Recent research advances have revealed that the modification of pristine MoS2 is a very effective approach to boost its HER performance, including improving the intrinsic activity of sites, increasing the number of edges, and enhancing the electrical conductivity. In this review, we focus on the recent progress on the modification strategies of MoS2 for enhanced electrocatalytic hydrogen evolution. Moreover, some urgent challenges in this field are also discussed to realize the large-scale application of the modified-MoS2 catalysts in industry.
All-weather solar-driven desalination systems, integrating photothermal evaporators with hybrid technologies, present a sustainable, cost-effective, and high-efficiency strategy for freshwater production. Despite significant advancements, previous reviews have predominantly focused on daytime evaporation, neglecting the broader scope of all-weather seawater evaporation. This review provides a comprehensive examination of the current status of all-weather seawater evaporators and their hybrid systems. Initially, the review details the system’s composition and operating principles, as well as the design criteria for high-performance evaporators. It then goes over various common photothermal conversion materials for seawater desalination, with a particular emphasis on those materials tailored for all-weather applications. It also offers an in-depth overview to the developed photothermal hybrid systems for all-weather seawater evaporation, including their working principles, the efficiency of evaporation across the day-night cycle, and their practical applications. Lastly, the existing challenges and potential research opportunities are thoroughly discussed.
Transition metal catalysts are widely used in the field of hydrogen production via water electrolysis. The surface state and near-surface environment of the catalysts greatly affect the efficiency of hydrogen production. Therefore, the rational design of surface engineering and near-surface engineering of transition metal catalysts can significantly improve the performance of water electrolysis. This review systematically introduces surface engineering strategies, including heteroatom doping, vacancy engineering, strain regulation, heterojunction effect, and surface reconstruction. These strategies optimize the surface electronic structure of the catalysts, expose more active sites, and promote the formation of highly active species, ultimately enhancing water electrolysis performance. Furthermore, near-surface engineering strategies, such as surface wettability, three-dimensional structure, high-curvature structure, external field assistance, and extra ion addition, are thoroughly discussed. These strategies expedite the mass transfer of reactants and gas products, improve the local chemical environment near the catalyst surface, and contribute toward achieving an industrial-level current density for overall water splitting. Finally, the key challenges faced by surface engineering and near-surface engineering of transition metal catalysts are highlighted and potential solutions are proposed. This review offers essential guidelines for the design and development of efficient transition metal catalysts for water electrolysis.
This review provides an in-depth analysis of the recent progress in bifunctional transition-metal catalysts for NWE, highlighting their critical role in both the degradation of nitrogenous pollutants and the generation of hydrogen energy.