With reference to the province of Novara in northwest Italy, this study aims to raise awareness about the environmental benefits that can derive from the use of alternative rice straw management practices to those currently in use, also highlighting how the use of these straws for energy purposes can be a valid alternative to the use of non-renewable resources. Using the LCA (Life Cycle Assessment) method, the two rice straw management practices currently in place (open field combustion and straw incorporation) were compared with an alternative strategy consisting in their collection and removal. The results show that removal of straw allows reducing the emissions of pollutants significantly: about one-hundredth of the PM (Particulate Matter) formation compared to the open-field burning and about one-tenth of the ozone depletion (CFCs, HCFCs, halons, etc.) compared to both the other two practices. Moreover, the LCA results show how the use of rice straw to produce energy as an alternative to conventional fuels helps to reduce the global warming potential of rice cultivation.
At steady state, in the governing equation of one-stage thermoelectric cooler, the heat resulting from Fourier conduction is balanced by heat generation due to the Joule and Thomson effects inside semiconductors. Since the heat flux observed at the junction of a semiconductor, r pair includes the Peltier effect and the Fourier heat flux caused by both the aforementioned contributions, the Thomson effect is easily masked by the Joule heat, which makes it elusive. With the aim of highlighting the contribution of the Thomson effect, measurements were carried out in the temperature range from 363 K to 213 K on different Peltier modules. The temperature dependence of the Seebeck and Thomson coefficients was evaluated as well as the electrical resistivity, and thermal conductivity of the Peltier modules examined. The results obtained show that the temperature dependence of the thermoelectric properties can reduce the cooling capacity of the Peltier module compared to what is declared in the technical datasheets of the commercial devices. The analyses allow us to conclude that an increase in the Thomson effect could have a positive effect on the performance of the Peltier only if it were possible to reduce the Joule contribution simultaneously.
The current energy transition highlights the importance not only of energy production, but also of its efficient storage, for which lithium-ion batteries are currently the leading technology. In many applications, these devices operate outdoors at temperatures below 0 °C, and consequently, their performance is reduced due to the lower mobility of the ions. With the aim of evaluating this decrease in performance, measurements were carried out on a commercial LiFePO4 module in the temperature range −20–+55 °C. The results show that the battery capacity decreases by 15% compared to the value measured at room temperature when the operating temperature drops to approximately −10 °C, and by 35% at approximately −20 °C. The paper also introduces a modified version of the Arrhenius kinetic model that allows for the analytical evaluation of the change in battery capacity as a function of temperature. The modified model proposes a quadratic dependence of the activation energy on the temperature through a temperature coefficient that for the two tested modules is equal to 8.0 × 10−5 eV/K2 and 6.7 × 10−5 eV/K2, respectively.