Airborne dust is one of the most important natural aerosols; it has various environmental impacts on air quality, ocean fertilization, and the global climate change. Asian dust, representing one of the major dust sources in the world, has been widely studied due to its long-range transport capability. However, its transport to the Arctic has been less investigated. In this study, two typical transport routes were identified based on the recorded dust events in China during 2011–2015. Accordingly, two specific Asian dust long-range transport events were selected and compared, i.e., one observed at Barrow, Alaska (traveled mostly over lands within 6–7 d), and the other one observed at Alert, Canada (traveled mostly over oceans within 7–8 d). The transport routes of the two dust events had been cross-validated by using air mass trajectory modeling, meteorology reanalysis data, ground-based aerosol columnar and profiling observations, and spaceborne remote sensing. It was found that different transport routes to the Arctic had divergent effects on the evolution of aerosol properties, revealing different mixing extents between dust, anthropogenic particles, smoke, and sea salts. Based on the Snow, Ice, and Aerosol Radiative (SNICAR) model, the albedo simulation indicated that dust and elemental carbon together reduced the surface albedo by 0.35 % to 2.63 % compared to the pure snow condition. This study implied that the dust long-range transport from China to the Arctic was ubiquitous and may be a potential contributor to the Arctic regional climate.

Ammonia in the atmosphere is essential for the formation of fine particles that impact air quality and climate. Despite extensive prior research to disentangle the relationship between ammonia and haze pollution, the role of ammonia in haze formation in high ammonia-emitting regions is still not well understood. Aiming to better understand secondary inorganic aerosol (sulfate, nitrate, ammonium – SNA) formation mechanisms under high-ammonia conditions, 1-year hourly measurement of water-soluble inorganic species (gas and particle) was conducted at a rural supersite in Shanghai. Exceedingly high levels of agricultural ammonia, constantly around 30 µg m⁻³, were observed. We find that gas-particle partitioning of ammonia (ε $\left({\mathrm{NH}}_{\mathrm{4}}^{+}\right)$ ), as opposed to ammonia concentrations, plays a critical role in SNA formation during the haze period. From an assessment of the effects of various parameters, including temperature (T), aerosol water content (AWC), aerosol pH, and activity coefficient, it seems that AWC plays predominant regulating roles for ε $\left({\mathrm{NH}}_{\mathrm{4}}^{+}\right)$ . We propose a self-amplifying feedback mechanism associated with ε $\left({\mathrm{NH}}_{\mathrm{4}}^{+}\right)$ for the formation of SNA, which is consistent with diurnal variations in ε $\left({\mathrm{NH}}_{\mathrm{4}}^{+}\right)$ , AWC, and SNA. Our results imply that a reduction in ammonia emissions alone may not reduce SNA effectively, at least at rural agricultural sites in China.

Speciated atmospheric mercury including gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particulate-bound mercury (PBM) were measured continuously for a 1-year period at a suburban site, representing a regional transport intersection zone, in east China. Annual mean concentrations of GEM, PBM, and GOM reached 2.77 ng m⁻³, 60.8 pg m⁻³, and 82.1 pg m⁻³, respectively. GEM concentrations were elevated in all the seasons except autumn. High mercury concentrations were related to winds from the south, southwest, and north of the measurement site. Combining analysis results from using various source apportionment methods, it was found that GEM concentration was higher when quasi-local sources dominated over long-range transport. Six source factors belonging to the anthropogenic sources of GEM were identified, including the common sectors previously identified (industrial and biomass burning, coal combustion, iron and steel production, cement production, and incineration), as well as an additional factor of shipping emissions (accounting for 19.5 % of the total), which was found to be important in east China where marine vessel shipping activities are intense. Emissions of GEM from natural surfaces were also found to be as important as those from anthropogenic sources for GEM observed at this site. Concurrences of high GOM concentrations with elevated O₃ and temperature, along with the lagged variations in GEM and GOM during daytime demonstrated that the very high GOM concentrations were partially ascribed to intense in situ oxidation of GEM. Strong gas–particle partitioning was also identified when PM_2.5 was above a threshold value, in which case GOM decreased with increasing PM_2.5.

To evaluate the effect of temporary emission control measures on air quality during the 2016 G20 summit held in Hangzhou, China, an intensive field campaign was conducted with a focus on aerosol chemistry and gaseous precursors from 15 August to 12 September 2016. The concentrations of fine particles were reduced during the intense emission control stages, with the reduction of carbonaceous matter being mostly responsible for this observed decrease. This, in turn, was mainly ascribed to the decrease of secondary organic aerosols via the suppression of daytime peak secondary organic carbon (SOC)formation. Although the regional joint control was enacted extending to the Yangtze River Delta region, the effect of long-range transport on the air quality of Hangzhou was ubiquitous. Unexpectedly high NO_x concentrations were observed during the control stage, when the strictest restriction on vehicles was implemented, owing to contributions from upstream populous regions such as Jiangsu and Shandong provinces. In addition, the continental outflow traveling over the ocean triggered a short pollution episode on the first day of the G20 summit, resulting in a significant enhancement of the nitrogen/sulfur oxidation rates. In the wake of the summit, all air pollutants evidently rebounded after the various control measures were lifted. Overall, the fraction of secondary inorganic aerosols (SIA; in this case sulfate, nitrate, and ammonium aerosols – SNA) in PM_2.5 increased as relative humidity increased; however, the overall concentration of PM_2.5 did not increase. Aerosol components that had distinctly different sources and formation mechanisms, e.g., sulfate/nitrate and elemental carbon, exclusively showed strong correlations during the regional/long-range transport episodes. The sulfate, nitrate, and ammonium to elemental carbon (SNA∕EC) ratio, which was used as a proxy for assessing the extent of secondary inorganic aerosol formation, was found to be significantly enhanced under transport conditions from northern China. This study highlighted that emission control strategies were beneficial for curbing particulate pollution, in addition to the fact that regional/long-range transport may offset local emission control effects to some extent.