Researchers have studied oil spills in open waters using remote sensors, but few have focused on extracting reflectance features of oil pollution on sea ice. An experiment was conducted on natural sea ice in Bohai Bay, China, to obtain the spectral reflectance of oil-contaminated sea ice. The spectral absorption index (SAI), spectral peak height (SPH), and wavelet detail coefficient (DWT d5) were calculated using stepwise multiple linear regression. The reflectances of some false targets were measured and analysed. The simulated false targets were sediment, iron ore fines, coal dust, and the melt pool. The measured reflectances were resampled using five common sensors (GF-2, Landsat8-OLI, Sentinel3-OLCI, MODIS, and AVIRIS). Some significant spectral features could discriminate between oil-polluted and clean sea ice. The indices correlated well with the oil area fractions. All of the adjusted R² values exceeded 0.9. The SPH model1, based on spectral features at 507–670 and 1627–1746 nm, displayed the best fitting. The resampled data indicated that these multi-spectral and hyper-spectral sensors could be used to detect crude oil on the sea ice if the effect of noise and spatial resolution are neglected. The spectral features and their identified changes may provide reference on sensor design and band selection.

Compared with hyperspectral remote sensing in visible-light, near infrared and short-wave infrared spectra, hyperspectral remote sensing in the thermal infrared spectrum has unique advantages, especially in the fields of mineral identification and pollution gas. At present, infrared hyperspectral imagers are rare and mainly airborne. In this paper, the basic principle and design features of a newly developed airborne thermal-infrared hyperspectral imaging system (ATHIS) are detailed, and separate validation experiments of laboratory and aerial remote sensing experiments are carried out. Measurements and comparative analysis of infrared emissivity spectra of the typical minerals were performed in the laboratory. In the summer of 2019, the instrument carried out flight tests in Hengdian Town, Dongyang City, Zhejiang Province, China. The results show that ATHIS can also accurately acquire the target emissivity spectrum. In the future, the instrument will also be used to carry out key technology verification and data-processing application research of space infrared hyperspectral imagers plan.

The emergence of hyperspectral thermal infrared imaging spectrometers makes it possible to retrieve both the land surface temperature (LST) and the land surface emissivity (LSE) simultaneously. However, few articles focus on the problem of how the instrument’s spectral parameters and instrument noise level affect the LST and LSE inversion errors. In terms of instrument development, this article simulated three groups of hyperspectral thermal infrared data with three common spectral parameters and each group of data includes tens of millions of simulated radiances of 1525 emissivity curves with 17 center wavelength shift ratios, 6 full width at half maximum (FWHM) change ratios and 6 noise equivalent differential temperatures (NEDTs) under 15 atmospheric conditions with 6 object temperatures, inverted them by two temperature and emissivity separation methods (ISSTES and ARTEMISS), and analyzed quantitatively the effects of the spectral parameters change and noise of an instrument on the LST and LSE inversion errors. The results show that: (1) center wavelength shifts and noise affect the inversion errors strongly, while FWHM changes affect them weakly; (2) the LST and LSE inversion errors increase with the center wavelength shift ratio in a quadratic function and increase with FWHM change ratio slowly and linearly for both the inversion methods, however they increase with NEDT in an S-curve for ISSTES while they increase with NEDT slightly and linearly for ARTEMISS. During the design and development of a hyperspectral thermal infrared instrument, it is highly recommended to keep the potential center wavelength shift within 1 band and keep NEDT within 0.1K (corresponding LST error < 1K and LSE error < 0.015) for normal applications and within 0.03K (corresponding LST error < 0.5K and LSE error < 0.01) for better application effect and level.

There are numerous algorithms that can be used to retrieve land surface temperature (LST) and land surface emissivity (LSE) from hyperspectral thermal infrared (HTIR) data. The algorithms are sensitive to a number of factors, where noise is difficult to handle due to its unpredictability. Although there is a lot of research regarding the influence of noise on retrieval errors, few studies have focused on the mechanism. In this study, we selected the automatic retrieval of temperature and emissivity using spectral smoothness (ARTEMISS) algorithm—the representative of the iterative spectral smoothness temperature-emissivity separation algorithm family—as the research object and proposed an improved algorithm. First, we analyzed the influence mechanism of noise on the retrieval errors of ARTEMISS in theory. Second, we carried out a simulation and inversion experiment and analyzed the relationship between instrument spectral resolution, noise level, the ARTEMISS parameter setting and the retrieval errors separately. Last, we proposed an improved method (resolution-degrade-based spectral smoothness algorithm, RDSS) based on the mechanism and law of the influence of noise on retrieval errors and provided corresponding suggestions on instrument design. The results show that RDSS improves the accuracy of temperature inversion and is more effective for thermal infrared data with a high noise level and high spectral resolution, which can reduce the LST inversion error by up to 0.75 K and the LSE median absolute deviation (MAD) by 31%. In the presence of noise in HTIR data, the RDSS algorithm performs better than the ARTEMISS algorithm in terms of temperature-emissivity separation.