The temporal delay in the water table's response to precipitation is a common phenomenon. Using a mathematical model, we developed a function that represents the recharge flux through unsaturated zones of varying thickness to model the delayed response of groundwater level due to precipitation. The recharge flux from the developed function was integrated into the analytical and numerical models to estimate the actual groundwater levels in the unsaturated zone. The analytical and numerical models accurately determined the actual groundwater levels. Additionally, calibrated hydraulic parameters from numerical estimates reflected the values measured in the actual aquifer, thereby highlighting the potential application of the developed function to wide‐ranging groundwater problems. Based on the recharge function, a recharge module can be developed for existing flow simulators to enhance groundwater modeling.
Radiocesium released by the severe nuclear accident and nuclear weapon test is a hazardous material. Illitic clays play a key role in the spatial distribution of radiocesium in groundwater environments due to selective uptake sites at the illite mineral, such as frayed edge sites. However, the cesium uptake capabilities of illitic clays are diverse, which could be associated with the illite crystallinity. This study was performed to determine the cesium uptake of illitic clays and evaluate the crystallinity effects on cesium uptake using statistical approaches. A total of 10 illitic clays showed various crystallinity, which was parameterized by the full width at half maximum (FWHM) at 10 Å XRD peak ranging from 0.15 to 0.64. The uptake behavior of illitic clays was well fitted with the Freundlich model (i.e., r2 > 0.946). The uptake efficiency of illitic clays increased with the decrease in dissolved cesium concentrations. The cesium uptake was significantly correlated with the FWHM and cation exchange capacity, suggesting that the uptake becomes higher with decreasing crystallinity through expansion of the edge site and/or formation of ion-exchangeable sites.
1 November 2018 in Science of The Total Environment