In order to systematically elucidate the combustion performance of fuel during sintering, this paper explores the influence of three factors, namely coal substitution for coke, quasi-particle structure and the coupling effect with reduction and oxidation of iron oxide, on fuel combustion characteristics, and carries out the kinetic calculation of monomer blended fuel (MBF) and quasi-granular fuel (QPF). The results show that replacing coke powder with anthracite can accelerate the whole combustion process. MBF and QPF are more consistent with the combustion law of the double-parallel random pore model. Although the quasi-particle structure increases the apparent activation energy of fuel combustion, it can also produce a heat storage effect on fuel particles, improve their combustion performance, and reduce the adverse effect of diffusion on the reaction process. In the early stage of reaction, the coupling between combustion of volatiles and reduction of iron oxide is obvious. The oxidation of iron oxide will occur again when the combustion reaction of fuel is weakened.
In this paper, Huolinhe lignite was selected as the lignite experimental sample, using microwave modification and ultrasonic modification separately as improvement methods. The three-dimensional molecular models of HLH before and after modification were established base on the parameters obtained by 13C NMR, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy (Raman), and Fourier transform infrared (FTIR). After the microwave treatment, the methylene carbon in the HLH coal sample structure mostly exists in the form of long straight chains, and after microwave and ultrasonic treatment, the -OH content of oxygen atoms in the coal sample increases, and form the CO- and the COO-. The proportion is decreasing. The models were adjusted and tested by the covalent bond concentration method and carbon chemical shift spectra calculation using Chemdraw software. A new method is proposed to study the structure and physicochemical properties of lignite modification from the molecular point of view through this study.
This study evaluated the effect of an increase in carbon content and the presence of the elements Mo and V on the microstructure and properties of the surfacing layer of stainless steel powder for knives and scissors production. Various types of high-quality stainless steel powder (5Cr13, 8Cr13, and 8Cr13MoV) were deposited on the surface of low-grade stainless steel used to produce knives and scissors (2Cr13). The microstructure, comprehensive hardness, wear resistance, impact toughness, and corrosion resistance of the stainless steel powder surfacing layers were tested and analyzed. Results indicate that the increase in carbon content and the presence of Mo and V improve the comprehensive hardness and wear resistance of the stainless steel powder surfacing layer, and both exert the superposition effect. However, the increase in carbon content and the presence of Mo and V slightly influence the impact toughness of the surfacing layer. In addition, the increase in carbon content significantly reduces the corrosion resistance of the surfacing layer. This adverse effect is reduced when Mo and V exist. Other advantages of the presence of Mo and V in the stainless steel powder surfacing layer include the refinement of grain size, reduction of carbide particle size, and improvement of the metallurgical bonding of the surfacing layer and the matrix.