Filippo Campana

Dr. Filippo Campana

Department of Chemistry, Biology and Biotechnology, University of Perugia, Perugia, Umbria, Italy
orcid

Research Focus & Metrics

Academic Career Length

9Years (2018-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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11 November 2020 in ACS Sustainable Chemistry & Engineering
Verified
Journal Article
Closed access
DVDiletta Morelli Venturi
Diletta Morelli Venturi
Filippo CampanaFilippo Campana
Filippo Campana
MFMarmottini Fabio
Marmottini Fabio
Ferdinando  CostantinoFerdinando Costantino
Ferdinando Costantino
Luigi VaccaroLuigi Vaccaro
Luigi Vaccaro

17 September 2020 in Journal of Materials Chemistry C
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Journal Article
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Filippo CampanaFilippo Campana
Filippo Campana
Choongik KimChoongik Kim
Choongik Kim
Assunta MarrocchiAssunta Marrocchi
Assunta Marrocchi
Luigi VaccaroLuigi Vaccaro
Luigi Vaccaro
A review on the recent efforts to select green solvents for processing organic semiconductors for thin film transistors (TFT) and organic photovoltaics (OPV) applications. A guide for the safe fabrication of high-performance devices.

19 March 2020 in Journal of Materials Chemistry C
Verified
Journal Article
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DHDongil Ho
Dongil Ho
JLJeongyeon Lee
Jeongyeon Lee
SPSangyun Park
Sangyun Park
YPYonghan Park
Yonghan Park
KCKwanghee Cho
Kwanghee Cho
Luigi VaccaroLuigi Vaccaro
Luigi Vaccaro
In this study, we explored a wide range of green solvents to process the semiconductor layer TIPS-PEN (6,13-bis(triisopropylsilylethynyl)pentacene), as well as to demonstrate potential generality, using several p- and n-type organic semiconductors, for the fabrication of organic thin-film transistors (OTFTs). Our data demonstrate that several different solvents enable good semiconductor film-forming morphologies and optimized TIPS-PEN TFT mobilities of ∼0.5–2 cm2 V−1 s−1, thus surpassing those of toxic chlorinated options. Furthermore, we utilized a green cellulose cinnamate-gate dielectric to fabricate TIPS-PEN OTFTs, where both the semiconductor and the dielectric were processed using green solvents demonstrating the feasibility of a more sustainable OTFT technology.

12 October 2023 in Bioresource Technology
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Journal Article
Open access
FVFederica Valentini
Federica Valentini
ECElisa Cerza
Elisa Cerza
Filippo CampanaFilippo Campana
Filippo Campana
Assunta MarrocchiAssunta Marrocchi
Assunta Marrocchi
Luigi VaccaroLuigi Vaccaro
Luigi Vaccaro
In pursuit of sustainable water management, the preparation of adsorbent materials via waste upcycling for water purification practices plays a decisive role. The sulphonated biochar, PiNe-SO3H, employed to target the methylene blue dye adsorption, was successfully synthesized via a mild, step-economical chemical carbonization-functionalization reaction. The presence of SO3H groups on the PiNe-SO3H surface played a critical role in significantly enhancing the adsorption capacity. The observed MB dye uptake was predominantly attributed to chemisorption processes as evidenced by the results from kinetics, thermodynamics, and isotherms. To further confirm the role of -SO3H in the adsorption mechanism, a comparison was made with other PiNe materials lacking sulphonic groups, highlighting the superior adsorption capacity of PiNe-SO3H. Additionally, a fast and efficient regeneration process was proposed to develop a truly waste minimized protocol, enabling the recovery of up to 94 % of the ethanolic mixture used during this step.

27 October 2020 in ACS Sustainable Chemistry & Engineering
Verified
Journal Article
Open access
Filippo CampanaFilippo Campana
Filippo Campana
BMBeatrice Maria Massaccesi
Beatrice Maria Massaccesi
SSStefano Santoro
Stefano Santoro
OPOriana Piermatti
Oriana Piermatti
Luigi VaccaroLuigi Vaccaro
Luigi Vaccaro
Herein, we report the use of nontoxic, water-miscible Polarclean as a safe dipolar aprotic solvent for the metal-catalyzed direct C2–H arylation of indoles using Pd/C as a catalyst. The developed method allows reaching excellent yields and regioselectivities, and it tolerates various substituents on both indole and diaryliodonium salt scaffolds. Polarclean is fully recoverable and reusable; it shows a very low leaching of the metal catalyst, allowing its complete recovery and reuse for at least six representative reaction runs.

30 May 2018 in Green Chemistry
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Journal Article
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VTValeria Trombettoni
Valeria Trombettoni
DSDaniele Sciosci
Daniele Sciosci
MBMaria Paola Bracciale
Maria Paola Bracciale
Filippo CampanaFilippo Campana
Filippo Campana
Maria Laura SantarelliMaria Laura Santarelli
Maria Laura Santarelli
Luigi VaccaroLuigi Vaccaro
Luigi Vaccaro
A pump-free, waste-minimized flow protocol exploiting the features of a specifically designed heterogeneous catalyst has been defined for a non-stop production of biomass-derived esters.