Kien Wen Sun

Prof. Kien Wen Sun

Department of Applied Chemistry, National Chiao Tung University
orcid

Research Focus & Metrics

Academic Career Length

27Years (2000-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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20 October 2017 in Scientific Reports
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Journal Article
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KWKai-Hung Wang
Kai-Hung Wang
LLLiang-Chen Li
Liang-Chen Li
Muthaiah ShellaiahMuthaiah Shellaiah
Muthaiah Shellaiah
Kien Wen SunKien Wen Sun
Kien Wen Sun
The structural and photophysical characteristics of MAPbBr3 single crystals prepared using the inverse temperature crystallization method are evaluated using temperature-dependent X-ray diffraction (XRD) and optical spectroscopy. Contrary to previous research reports on perovskite materials, we study phase transitions in crystal lattice structures accompanied with changes in optical properties expand throughout a wide temperature range of 300–1.5 K. The XRD studies reveal several phase transitions occurred at ~210 K, ~145 K, and ~80 K, respectively. The coexistence of two different crystallographic phases was observed at a temperature below 145 K. The emission peaks in the PL spectra are all asymmetric in line shape with weak and broad shoulders near the absorption edges, which are attributed to the Br atom vacancy on the surface of the crystals. The time-resolved PL measurements reveal the effect of the desorption/adsorption of gas molecules on the crystal surface on the PL lifetimes. Raman spectroscopy results indicate the strong interplays between cations and different halide atoms. Lastly, no diamagnetic shift or split in emission peaks can be observed in the magneto-PL spectra even at an applied magnetic field up to 5 T and at a temperature as low as 1.5 K.

14 July 2020 in Chemosensors
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Muthaiah ShellaiahMuthaiah Shellaiah
Muthaiah Shellaiah
Kien Wen SunKien Wen Sun
Kien Wen Sun
Recently, perovskite-based nanomaterials are utilized in diverse sustainable applications. Their unique structural characteristics allow researchers to explore functionalities towards diverse directions, such as solar cells, light emitting devices, transistors, sensors, etc. Many perovskite nanomaterial-based devices have been demonstrated with extraordinary sensing performance to various chemical and biological species in both solid and solution states. In particular, perovskite nanomaterials are capable of detecting small molecules such as O2, NO2, CO2, etc. This review elaborates the sensing applications of those perovskite materials with diverse cations, dopants and composites. Moreover, the underlying mechanisms and electron transport properties, which are important for understanding those sensor performances, will be discussed. Their synthetic tactics, structural information, modifications and real time sensing applications are provided to promote such perovskite nanomaterials-based molecular designs. Lastly, we summarize the perspectives and provide feasible guidelines for future developing of novel perovskite nanostructure-based chemo- and biosensors with real time demonstration.

10 June 2021 in ACS Applied Materials & Interfaces
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Journal Article
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Muthaiah ShellaiahMuthaiah Shellaiah
Muthaiah Shellaiah
YCYu-Ting Chen
Yu-Ting Chen
NTNatesan Thirumalaivasan
Natesan Thirumalaivasan
BABasheer Aazaad
Basheer Aazaad
KAKamlesh Awasthi
Kamlesh Awasthi
NONobuhiro Ohta
Nobuhiro Ohta

7 February 2022 in ACS Applied Nano Materials
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Journal Article
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Muthaiah ShellaiahMuthaiah Shellaiah
Muthaiah Shellaiah
KAKamlesh Awasthi
Kamlesh Awasthi
SCSarala Chandran
Sarala Chandran
BABasheer Aazaad
Basheer Aazaad
Kien Wen SunKien Wen Sun
Kien Wen Sun
MLMing-Chang Lin
Ming-Chang Lin

21 July 2022 in Biosensors
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Muthaiah ShellaiahMuthaiah Shellaiah
Muthaiah Shellaiah
Kien Wen SunKien Wen Sun
Kien Wen Sun
Aggregation-induced emission (AIE) is a unique research topic and property that can lead to a wide range of applications, including cellular imaging, theranostics, analyte quantitation and the specific detection of biologically important species. Towards the development of the AIE-active materials, many aromatic moieties composed of tetraphenylethylene, anthracene, pyrene, etc., have been developed. Among these aromatic moieties, pyrene is an aromatic hydrocarbon with a polycyclic flat structure containing four fused benzene rings to provide an unusual electron delocalization feature that is important in the AIE property. Numerous pyrene-based AIE-active materials have been reported with the AIE property towards sensing, imaging and theranostics applications. Most importantly, these AIE-active pyrene moieties exist as small molecules, Schiff bases, polymers, supramolecules, metal-organic frameworks, etc. This comprehensive review outlines utilizations of AIE-active pyrene-based materials on the imaging and theranostics studies. Moreover, the design and synthesis of these pyrene-based molecules are delivered with discussions on their future scopes.

12 July 2011 in Optics Express
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Journal Article
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JCJ.Y. Chen
J.Y. Chen
WCW.-L. Chang
W.-L. Chang
CHC.K. Huang
C.K. Huang
Kien Wen SunKien Wen Sun
Kien Wen Sun
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