Amorphous zirconium oxide nanoparticles (ZrO₂) have been used for the first time, to modify carbon paste electrode (CPE) and used as a sensor for the electrochemical determination of gallic acid (GA). The voltammetric results of the ZrO₂ nanoparticles-modified CPE showed efficient electrochemical oxidation of gallic acid, with a significantly enhanced peak current from 261 µA ± 3 to about 451 µA ± 1. The modified surface of the electrode and the synthesised zirconia nanoparticles were characterised by scanning electrode microscopy (SEM), Energy-dispersive x-ray spectroscopy (EDXA), X-ray powdered diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). Meanwhile, the electrochemical behaviour of GA on the surface of the modified electrode was studied using differential pulse voltammetry (DPV), showing a sensitivity of the electrode for GA determination, within a concentration range of 1 × 10⁻⁶ mol L⁻¹ to 1 × 10⁻³ mol L⁻¹ with a correlation coefficient of R² of 0.9945 and a limit of detection of 1.24 × 10⁻⁷ mol L⁻¹ (S/N = 3). The proposed ZrO₂ nanoparticles modified CPE was successfully used for the determination of GA in red and white wine, with concentrations of 0.103 mmol L⁻¹ and 0.049 mmol L⁻¹ respectively.

Sliding wear evaluation of nanostructured coatings deposited by Suspension High Velocity Oxy-Fuel (S-HVOF) and conventional HVOF (Jet Kote (HVOF-JK) and JP5000 (HVOF-JP)) spraying were evaluated. S-HVOF coatings were nanostructured and deposited via an aqueous based suspension of the WC-Co powder, using modified HVOF (TopGun) spraying. Microstructural evaluations of these hardmetal coatings included X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) equipped with Energy Dispersive X-ray Spectroscopy (EDX). Sliding wear tests on coatings were conducted using a ball-on-flat test rig against steel, silicon nitride (Si3N4) ceramic and WC-6Co balls. Results indicated that nanosized particles inherited from the starting powder in S-HVOF spraying were retained in the resulting coatings. Significant changes in the chemical and phase composition were observed in the S-HVOF coatings. Despite decarburization, the hardness and sliding wear resistance of the S-HVOF coatings was comparable to the HVOF-JK and HVOF-JP coatings. The sliding wear performance was dependent on the ball-coating test couple. In general a higher ball wear rate was observed with lower coating wear rate. Comparison of the total (ball and coating) wear rate indicated that for steel and ceramic balls, HVOF-JP coatings performed the best followed by the S-HVOF and HVOF-JK coatings. For the WC-Co ball tests, average performance of S-HVOF was better than that of HVOF-JK and HVOF-JP coatings. Changes in sliding wear behavior were attributed to the support of metal matrix due to relatively higher tungsten content, and uniform distribution of nanoparticles in the S-HVOF coating microstructure. The presence of tribofilm was also observed for all test couples. / Highlights - Tribomechanical comparison of conventional and nanocomposite suspension coatings. / Wear of hardmetal coatings against metal, ceramic and sintered carbide couples. / Structure property relationships of nanostructured WC–Co coatings. / Performance was couple depended and tribofilm was observed in all test couples. / Mathematical correlations provide a fit to the wear rate