Covalent functionalization of the surface is crucial in 2D materials because of their atomic thinness, large surface-to-volume ratio, and uniform surface chemical potential.

Temperature control of the lithium-ion pouch cells is crucial for smooth operation, longevity and enhanced safety in the battery-operated electric vehicles. Investigating the thermal behavior of lithium-ion pouch cells and optimizing the cooling performance are required to accomplish better performance, long life, and enhanced safety. In the present study, the cooling performance characteristics of 20 Ah lithium-ion pouch cell with cold plates along both surfaces are investigated by varying the inlet coolant mass flow rates and the inlet coolant temperatures. The inlet coolant mass flow rate is varied from 0.000833 kg/s to 0.003333 kg/s, and the inlet coolant temperature is varied from 5 °C to 35 °C. In addition, the effects of the cold plate geometry parameter on cooling performance of 20 Ah lithium-ion pouch cell are studied by varying the number of the channels from 4 to 10. The maximum temperature and difference between the maximum and the minimum temperatures are considered as important criteria for cooling performance evaluation of the 20 Ah lithium-ion pouch cell with cold plates along both surfaces. The cooling energy efficiency parameter (β) and the pressure drop for 20 Ah lithium-ion pouch cell with cold plates along both surfaces are also reported. The study shows that enhanced cooling energy efficiency is accompanied with low inlet coolant temperature, low inlet coolant mass flow rate, and a high number of the cooling channels. As a result, the temperature distribution, the pressure drop, and the cooling energy efficiency parameter (β) of the 20 Ah lithium-ion pouch cell with cold plates along both surfaces are provided, and could be applied for optimizing the cooling performances of the thermal management system for lithium-ion batteries in electric vehicles.

Droplet microfluidics performed in poly(methyl methacrylate) (PMMA) microfluidic devices resulted in significant wall wetting by water droplets formed in a liquid–liquid segmented flow when using a hydrophobic carrier fluid such as perfluorotripropylamine (FC-3283). This wall wetting led to water droplets with nonuniform sizes that were often trapped on the wall surfaces, leading to unstable and poorly controlled liquid–liquid segmented flow. To circumvent this problem, we developed a two-step procedure to hydrophobically modify the surfaces of PMMA and other thermoplastic materials commonly used to make microfluidic devices. The surface-modification route involved the introduction of hydroxyl groups by oxygen plasma treatment of the polymer surface followed by a solution-phase reaction with heptadecafluoro-1,1,2,2-tetrahydrodecyl trichlorosilane dissolved in fluorocarbon solvent FC-3283. This procedure was found to be useful for the modification of PMMA and other thermoplastic surfaces, including polycyclic olefin copolymer (COC) and polycarbonate (PC). Angle-resolved X-ray photoelectron spectroscopy indicated that the fluorination of these polymers took place with high surface selectivity. This procedure was used to modify the surface of a PMMA droplet microfluidic device (DMFD) and was shown to be useful in reducing the wetting problem during the generation of aqueous droplets in a perfluorotripropylamine (FC-3283) carrier fluid and could generate stable segmented flows for hours of operation. In the case of PMMA DMFD, oxygen plasma treatment was carried out after the PMMA cover plate was thermally fusion bonded to the PMMA microfluidic chip. Because the appended chemistry to the channel wall created a hydrophobic surface, it will accommodate the use of other carrier fluids that are hydrophobic as well, such as hexadecane or mineral oils.

Microfluidic devices where the microchannel walls were decorated with micro and nanostructures were fabricated using 3D nanomolding. Using 3D molded microfluidic devices with microchannel walls decorated with microscale gratings, the fluid mixing behavior was investigated through experiments and numerical simulation. The use of microscale gratings in the micromixer was predicated by the fact that large obstacles in a microchannel enhances the mixing performance. Slanted ratchet gratings on the channel walls resulted in a helical flow along the microchannel, thus increasing the interfacial area between fluids and cutting down the diffusion length. Increasing the number of walls decorated with continuous ratchet gratings intensified the strength of the helical flow, enhancing mixing further. When ratchet gratings on the surface of the top cover plate were aligned in a direction to break the continuity of gratings from the other three walls, a stack of two helical flows was formed one above each other. This work concludes that the 3D nanomolding process can be a cost-effective tool for scaling-up the fabrication of microfluidic mixers with improved mixing efficiencies.

While traditional oil recovery methods are limited in terms of meeting the overall oil demands, enhanced oil recovery (EOR) techniques are being continually developed to provide a principal portion of our energy demands. Chemical EOR (cEOR) is one of the EOR techniques that shows an efficient oil recovery factor in a number of oilfields with low salinity and temperature ranges. However, the application of cEOR under the harsh conditions of reservoirs where most of today’s crude oils come from remains a challenge. High temperatures, the presence of ions, divalent ions, and heterogeneous rock structures in such reservoirs restrict the application of cEOR. Polymer solutions, surfactants, alkaline-based solutions, and complex multi-components of them are common chemical displacing fluids that failed to show successful recovery results in hostile conditions for various reasons. Wormlike micellar solutions (WMS) are viscoelastic surfactants that possess advantageous characteristics for overcoming current cEOR challenges. In this study, we first review the major approaches and challenges of commonly used chemical agents for cEOR applications. Subsequently, we review special characteristics of WMS that make them promising materials for the future of cEOR.