Two approaches were designed to identify the echoes of clear air and precipitation when both coexist in the very-high-frequency (VHF) radar spectra: contour-based and peak-finding methods. The contour-based approach was used to model a 2D Doppler spectra to determine the locations of multiple spectral humps, and the peak-finding approach was used to find the spectral peaks on request. Grouping, sifting, and Gaussian fitting were performed further for such obtained contour centres and spectral peaks to yield Doppler velocities and spectral widths. In general, the two approaches resulted in corresponding outcomes and can be complementary to find the spectral peaks as fully as possible. The Doppler velocities retrieved from the two approaches were cooperatively used to develop an effective process of Doppler profiling for treating a great amount of radar data, which was validated with the radar data collected during a rainy and strongly convective atmosphere. As an application of Doppler profiling results, the hydrometeor parameters measured by a dual-polarized microwave radiometer were investigated jointly with radar observation, showing that a strong updraft air could bring the liquid water to a height above the melting layer and then the Bergeron effect and coalescence processes on formation of ice crystals and graupel particles occur accordingly.