For glass-forming substances, we show that the ratio can be predicted quantitatively from the coupling model. Here is the glassy state activation enthalpy of the Johari-Goldstein β relaxation, is the glass transition temperature of the α relaxation, and R is the gas constant. The calculated value is in good agreement with the experimental value in many glass formers. The results locate the origin of this cross correlation between of the Johari-Goldstein β relaxation and of the α relaxation, although there are some notable exceptions to this cross correlation.
30 August 2005 in The Journal of Physical Chemistry B