Volatile organic compounds (VOCs) play an important role in atmospheric chemistry. Primary VOCs take part in chemical and photochemical reactions, contributing to ozone (O₃) and secondary organic aerosol (SOA) formation, which may cause air pollution problems. High VOC concentrations might lead to dizziness, nausea, headaches, genotoxicity, reproductive weakness, and other diseases harmful to human health. Several studies have been performed to analyze the components, variations, or sources of VOCs at the ground level. In contrast, studies of the vertical distribution characteristics of VOCs are scarce, and the VOC potential for O₃ formation in the boundary layer is not yet well understood. To better understand the VOC vertical variation regularities and related reasons in temporal and spatial dimensions, thus to deepen the understanding of their effects on O₃ and SOA formation in the vertical direction and to identify the existing gaps in VOC vertical distributions, this study reviewed VOC sampling techniques, VOC vertical distribution characteristics, VOC diffusion models, and effects caused by VOCs. This work can be a valuable reference for decision making regarding environmental and health problems.

The airport and its surrounding areas are home to a variety of pollution sources, and air pollution is a recognized health concern for local populated regions. Submicron particulate matter (PM₁ with an aerodynamic diameter of <1 mm) is a typical pollutant at airports, and the enrichment of heavy metals (HMs) in PM₁ poses a great threat to human health. To comprehensively assess the source-specific health effects of PM₁-bound HMs in an airport community, PM₁ filter samples were collected around the Tianjin Binhai International Airport for 12 h during the daytime and nighttime, both in the spring and summer, and 10 selected HMs (V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd, and Pb) were analyzed. The indicatory elements of aircraft emissions were certified as Zn and Pb, which accounted for more than 60% of the sum concentration of detected HMs. The health risks assessment showed that the total non-cancer risks ($TNCRs$) of PM₁-bound HMs were 0.28 in the spring and 0.23 in the summer, which are lower than the safety level determined by the USEPA, and the total cancer risk ($TCR$) was 2.37 × 10⁻⁵ in the spring and 2.42 × 10⁻⁵ in the summer, implying that there were non-negligible cancer risks in the Tianjin Airport Community. After source apportionment with EF values and PMF model, four factors have been determined in both seasons. Consequently, the source-specific health risks were also evaluated by combining the PMF model with the health risk assessment model. For non-cancer risk, industrial sources containing high concentrations of Mn were the top contributors in both spring (50.4%) and summer (44.2%), while coal combustion with high loads of As and Cd posed the highest cancer risk in both seasons. From the perspective of health risk management, targeted management and control strategies should be adopted for industrial emissions and coal combustion in the Tianjin Airport Community.

Water-soluble inorganic ions (WSIIs) can increase the hygroscopicity of aerosols, which will transform aerosols into larger sizes and reduce visibility by enhancing light scattering. To explore the characteristics of WSII concentrations and their impacts on visibility in a coastal airport, in this study, PM_1.0 samples at two monitoring sites (including airport site and background site) were collect in spring and summer, and 12 species of ions were detected. In general, secondary water-soluble inorganic ions (SNA, including ${\mathrm{SO}}_4^{2-}$, ${\mathrm{NO}}_3^{-}$ and ${\mathrm{NH}}_4^{+}$) and ${\mathrm{Ca}}^{2+}$ were the dominant WSIIs in PM_1.0, contributing about 89% to 95% of the total measured ions. The continental contributions of ${\mathrm{SO}}_4^{2-}$, ${\mathrm{K}}^{+}$, and ${\mathrm{Ca}}^{2+}$ accounted for more than 60% during the whole period, while Na⁺ and ${\mathrm{Cl}}^{-}$ were mainly from marine sources. The source identification showed that airport emissions were a major source at the sampling site and significantly contributed to the levels of sulfate, nitrate, and ammonium. Agricultural activities were the dominant sources impacting visibility in spring, while airport emissions and secondary inorganic aerosols were the main components affecting visibility in summer. Therefore, improving atmospheric visibility in coastal airport areas should focus on reducing the precursors of secondary particulates and reducing biomass-burning activities.