The present study is devoted to the extraction of rare-earth metals (REMs) from a high-silica ore found in one of the deposits in Kazakhstan. The ore was processed in a mixture with sulfuric acid at 200°C (sulphatization) and subsequently followed by water leaching of the sulphate product (sinter), REMs were extracted into the solution. Precipitation of the REMs-containing hydrate product from the sulfate solution was carried out with sodium hydroxide. In order to obtain the REMs-containing nitrate solution, the precipitate was dissolved in nitric acid. REMs solvent extraction from nitrate solutions was carried out with tributyl phosphate (TBP).

The article presents the results of studying the determination of the influence of the nature of a number of mineral reagents (solutions of hydrochloric, nitric, sulfur and phosphoric acids, as well as sodium hydroxide and carbonate) on silicon extraction in solution upon he leaching of phosphorus production slags. The results of studying the process of the breakdown of phosphorus production slag with sodium carbonate solutions depending on various physicochemical parameters are provided. The optimum conditions of main technological operations were found and the main parameters that influence the morphological structure and size of precipitated silica particles were established. The influence of the conditions of washing of carbonate-silicate cake on its chemical, phase, and granulometric composition has been studied. Scaled-up laboratory tests have been carried out and a technology for processing phosphorus production slags to produce mineral fillers was developed on their basis. Conclusions on the applicability of pilot batches of white soot in tire and paint industries and carbonate-silicate fillers in construction industry and agriculture were obtained.

The article presents the research results for the synthesis of inorganic sorbents based on manganese oxide compounds. It shows the results of the lithium sorption from brines with the use of synthesized sorbents. The effect of temperature, the molar ratio of Li/Mn, and the duration for obtaining a lithium-manganese precursor and its acid treatment was studied. The sorption characteristics of the synthesized sorbents were studied. The effect of the ratio of the sorbent mass to the brine volume and the duration of the process on the sorption of lithium from brine were studied. In this case, the sorbent recovery of lithium was ~86%. A kinetic model of the lithium sorption from brine on a synthesized sorbent was determined. The kinetics of the lithium sorption was described by a pseudo-second-order model, which implies limiting the speed of the process due to a chemical reaction.

This article presents studies on the ammonium fluoride processing of dusts from the reduction smelting of ilmenite concentrate with separation of silicon to obtain titanium dioxide. Optimal conditions for pyrohydrolysis of titanium fluorides were determined. The effects of temperature and duration on the process were studied. The optimal conditions for pyrohydrolysis of titanium fluorides were a temperature of 600 °C and duration of 240–300 min. The degree of titanium fluoride conversion to titanium oxide was 99.5% at these conditions. Titanium dioxide obtained by pyrohydrolysis of titanium fluorides was purified from iron, chromium, and manganese impurities. The effect of hydrochloric acid solution concentration, S:L ratio, and the process duration on the purification degree of titanium fluoride pyrohydrolysis was studied. The following optimum purification conditions were determined: hydrochloric acid solution concentration 12.5–15 wt%, temperature 25–30 °C, S:L = 1:6÷8, duration 20–30 min. The purified titanium dioxide consisted mainly of anatase. The pigmented titanium dioxide of rutile modification with 99.8 wt% TiO₂ was obtained after calcination at 900 °C for 120 min.