Noble metal nanoparticles (NPs) are important in many applications, including light trapping of photovoltaic cells, photoelectrochemical applications, etc. The present study reports the formation of silver NPs from the as-deposited silver coatings on fused silica substrates by solid-state dewetting induced by high-current intense pulsed ion beam (IPIB) irradiation. We described the effects of IPIB irradiation with different ion beam current densities and numbers of pulses on NP morphology and compared the results with conventional rapid thermal annealing (RTA). IPIB irradiation enables superfast heating (higher than 10⁹ K/s) and cooling, providing a superfast annealing solid-state dewetting mechanism. Our results demonstrate that the sphericity of silver NPs is enhanced after IPIB irradiation relative to RTA-annealed silver NPs. Our results suggest further possibilities of shape and sphericity control of silver NPs with very fast heating/cooling annealing rates.

The spin-coating method was used to create double-layered porous TiO₂ films with high photoelectrochemical activity for potential use as a photoelectrode in fuel cells.

Optimized ZnO–Ga ₂ O ₃ thin films for PEC water splitting by tuning thickness, annealing, and environment, enhancing photocurrent density and revealing key structure–performance links for scalable solar hydrogen production.

The photoelectrochemical (PEC) activity of metal oxide photoelectrodes for water-splitting applications can be boosted in several different ways. In this study, we showed that PEC activity can be significantly improved with a double-layer (crystalline-amorphous) configuration of WO₃ thin films irradiated with intense pulsed ion beams (IPIB) of a nanosecond duration. It was found that IPIB irradiation promotes the formation of crystalline and sponge-like WO₃ structures on the surface. Due to an increase in the active surface and light scattering in irradiated samples, photocurrent generation increased by ~80% at 1.23 reversible hydrogen electrodes (RHE).