Armand Budzianowski

Dr. Armand Budzianowski

National Centre for Nuclear Research, Otwock, Mazowieckie, Poland
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Research Focus & Metrics

Academic Career Length

26Years (2001-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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17 January 2006 in Acta crystallographica Section B, Structural science, crystal engineering and materials
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Armand BudzianowskiArmand Budzianowski
Armand Budzianowski
AKAndrzej Katrusiak
Andrzej Katrusiak

15 March 2011 in Dalton Transactions
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KFKarol J. Fijalkowski
Karol J. Fijalkowski
RGRadostina V. Genova
Radostina V. Genova
YFYaroslav Filinchuk
Yaroslav Filinchuk
Armand BudzianowskiArmand Budzianowski
Armand Budzianowski
MDMariana Derzsi
Mariana Derzsi
WGWojciech Grochala
Wojciech Grochala
We describe the successful synthesis of the first mixed-cation (pseudoternary) amidoborane, Na[Li(NH2BH3)2], with theoretical hydrogen capacity of 11.1 wt%. Na[Li(NH2BH3)2] crystallizes triclinic (P) with a = 5.0197(4) Å, b = 7.1203(7) Å, c = 8.9198(9) Å, α = 103.003(6)°, β = 102.200(5)°, γ = 103.575(5)°, and V = 289.98(5) Å3 (Z = 2), as additionally confirmed by Density Functional Theory calculations. Its crystal structure is topologically different from those of its orthorhombic LiNH2BH3 and NaNH2BH3 constituents, with distinctly different coordination spheres of Li (3 N atoms and 1 hydride anion) and Na (6 hydride anions). Na[Li(NH2BH3)2], which may be viewed as a product of a Lewis acid (LiNH2BH3)/Lewis base (NaNH2BH3) reaction, is an important candidate for a novel lightweight hydrogen storage material. The title material decomposes at low temperature (with onset at 75 °C, 6.0% mass loss up to 110 °C, and an additional 3.0% up to 200 °C) while evolving hydrogen contaminated with ammonia.

19 November 2008 in The Journal of Physical Chemistry B
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Armand BudzianowskiArmand Budzianowski
Armand Budzianowski
AKAndrzej Katrusiak
Andrzej Katrusiak
Marek SzafrańskiMarek Szafrański
Marek Szafrański

1 June 2010 in Journal of Alloys and Compounds
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RGRadostina V. Genova
Radostina V. Genova
KFKarol J. Fijalkowski
Karol J. Fijalkowski
Armand BudzianowskiArmand Budzianowski
Armand Budzianowski
WGWojciech Grochala
Wojciech Grochala