High-resolution Doppler-resolved spectroscopy has opened up a new window into the atmospheres of both transiting and non-transiting exoplanets. Here, we present VLT/UVES observations of a transit of WASP-121b, an ‘ultra-hot’ Jupiter previously found to exhibit a temperature inversion and detections of multiple species at optical wavelengths. We present initial results using the blue arm of UVES (≈3700–5000 Å), recovering a clear signal of neutral Fe in the planet’s atmosphere at >8$\, \sigma$, which could contribute to (or even fully explain) the temperature inversion in the stratosphere. However, using standard cross-correlation methods, it is difficult to extract physical parameters such as temperature and abundances. Recent pioneering efforts have sought to develop likelihood ‘mappings’ that can be used to directly fit models to high-resolution data sets. We introduce a new framework that directly computes the likelihood of the model fit to the data, and can be used to explore the posterior distribution of parametrised model atmospheres via MCMC techniques. Our method also recovers the physical extent of the atmosphere, as well as account for time- and wavelength-dependent uncertainties. We measure a temperature of $3710^{+490}_{-510}$ K, indicating a higher temperature in the upper atmosphere when compared to low-resolution observations. We also show that the Fe i signal is physically separated from the exospheric Fe ii. However, the temperature measurements are highly degenerate with aerosol properties; detection of additional species, using more sophisticated atmospheric models, or combining these methods with low-resolution spectra should help break these degeneracies.

We report high-resolution spectroscopic detection of TiO molecular signature in the day-side spectra of WASP-33b, the second hottest known hot Jupiter. We used the High Dispersion Spectrograph (HDS; R ∼ 165,000) on the Subaru telescope in the wavelength range of 0.62–0.88 μm to obtain the day-side spectra of WASP-33b. We suppress and correct the systematic effects of the instrument and the telluric and stellar lines using the SYSREM algorithm after the selection of good orders based on Barnard’s star and other M-type stars. We detect a 4.8σ signal at an orbital velocity of km s⁻¹ and systemic velocity of km s⁻¹, which agree with the derived values from a previous analysis of the primary transit. Our detection with the temperature inversion model implies the existence of a stratosphere in its atmosphere; however, we were unable to constrain the volume mixing ratio of the detected TiO. We also measure the stellar radial velocity and use it to obtain a more stringent constraint on the orbital velocity, km s⁻¹. Our results demonstrate that high-dispersion spectroscopy is a powerful tool to characterize the atmosphere of an exoplanet, even in the optical wavelength range, and shows a promising potential in using and developing similar techniques with high-dispersion spectrograph on current 10 m class and future extremely large telescopes.

We analyse the transmission spectra of KELT-20b/MASCARA-2b to search for possible thermal inversion agents. The data consist of three transits obtained using HARPSN and one using CARMENES. We removed stellar and telluric lines before cross-correlating the residuals with spectroscopic templates produced using a 1D plane-parallel model, assuming an isothermal atmosphere and chemical equilibrium at solar metallicity. Using a likelihood-mapping method, we detect Fe i at > 13σ, Ca ii H$\&$K at > 6σ and confirm the previous detections of Fe ii, Ca ii IR Triplet, and Na i D. The detected signal of Fe i is shifted by −3.4 ± 0.4 km s−1 from the planetary rest frame, which indicates a strong day–night wind. Our likelihood-mapping technique also reveals that the absorption features of the detected species extend to different altitudes in the planet’s atmosphere. Assuming that the line lists are accurate, we do not detect other potential thermal inversion agents (NaH, MgH, AlO, SH, CaO, VO, FeH, and TiO) suggesting that non-chemical equilibrium mechanisms (e.g. a cold-trap) might have removed Ti- and V-bearing species from the upper atmosphere. Our results, therefore, show that KELT-20b/MASCARA-2b cannot possess an inversion layer caused by a TiO/VO-related mechanism. The presence of an inversion layer would therefore likely be caused by metal atoms such as Fe i and Fe ii. Finally, we report a double-peak structure in the Fe i signal in all of our data sets that could be a signature of atmospheric dynamics. However, further investigation is needed to robustly determine the origin of the signal.

Thermal inversions have long been predicted to exist in the atmospheres of ultra-hot Jupiters. However, the detection of two species thought to be responsible – titanium oxide and vanadium oxide – remains elusive. We present a search for TiO and VO in the atmosphere of the ultra-hot Jupiter WASP-121b (T_eq ≳ 2400 K), an exoplanet with evidence of VO in its atmosphere at low resolution which also exhibits water emission features in its dayside spectrum characteristic of a temperature inversion. We observed its transmission spectrum with the UV-Visual Echelle Spectrograph at the Very Large Telescope and used the cross-correlation method – a powerful tool for the unambiguous identification of the presence of atomic and molecular species – in an effort to detect whether TiO or VO were responsible for the observed temperature inversion. No evidence for the presence of TiO or VO was found at the terminator of WASP-121b. By injecting signals into our data at varying abundance levels, we set rough detection limits of [VO] ≲−7.9 and [TiO] ≲−9.3. However, these detection limits are largely degenerate with scattering properties and the position of the cloud deck. Our results may suggest that neither TiO or VO are the main drivers of the thermal inversion in WASP-121b; however, until a more accurate line list is developed for VO, we cannot conclusively rule out its presence. Future works will consist of a search for other strong optically-absorbing species that may be responsible for the excess absorption in the red-optical.

We report the first detection of a hydroxyl radical (OH) emission signature in the planetary atmosphere outside the solar system, in this case, in the dayside of WASP-33b. We analyze high-resolution near-infrared emission spectra of WASP-33b taken using the InfraRed Doppler spectrograph on the 8.2 m Subaru telescope. The telluric and stellar lines are removed using a detrending algorithm, SysRem. The residuals are then cross-correlated with OH and H₂O planetary spectrum templates produced using several different line lists. We check and confirm the accuracy of OH line lists by cross-correlating with the spectrum of GJ 436. As a result, we detect the emission signature of OH at K _p of km s⁻¹ and v _sys of −0.3 km s⁻¹ with a signal-to-noise ratio (S/N) of 5.4 and a significance of 5.5σ. Additionally, we marginally detect H₂O emission in the H-band with an S/N of 4.0 and a significance of 5.2σ using the POKAZATEL line list. However, no significant signal is detected using the HITEMP 2010, which might be due to differences in line positions and strengths, as well as the incompleteness of the line lists. Nonetheless, this marginal detection is consistent with the prediction that H₂O is mostly thermally dissociated in the upper atmosphere of the ultra-hot Jupiters. Therefore, along with CO, OH is expected to be one of the most abundant O-bearing molecules in the dayside atmosphere of ultra-hot Jupiters and should be considered when studying their atmospheres.

Ultrahot Jupiters (UHJs) present excellent targets for atmospheric characterization. Their hot dayside temperatures (T ≳ 2200 K) strongly suppress the formation of condensates, leading to clear and highly inflated atmospheres extremely conducive to transmission spectroscopy. Recent studies using optical high-resolution spectra have discovered a plethora of neutral and ionized atomic species in UHJs, placing constraints on their atmospheric structure and composition. Our recent work has presented a search for molecular features and detection of Fe i in the UHJ WASP-121b using Very Large Telescope (VLT)/UV–Visual Echelle Spectrograph (UVES) transmission spectroscopy. Here, we present a systematic search for atomic species in its atmosphere using cross-correlation methods. In a single transit, we uncover potential signals of 17 atomic species that we investigate further, categorizing five as strong detections, three as tentative detections, and nine as weak signals worthy of further exploration. We confirm previous detections of Cr i, V i, Ca i, K i, and exospheric H i and Ca ii made with the High Accuracy Radial velocity Planet Searcher (HARPS) and the Echelle SPectrograph for Rocky Exoplanets and Stable Spectroscopic Observations (ESPRESSO), and independently re-recover our previous detection of Fe i at 8.8σ using both the blue and red arms of the UVES data. We also add a novel detection of Sc ii at 4.2σ. Our results further demonstrate the richness of UHJs for optical high-resolution spectroscopy.