The search for habitable environments and biomarkers in exoplanetary atmospheres is the holy grail of exoplanet science. The detection of atmospheric signatures of habitable Earth-like exoplanets is challenging owing to their small planet–star size contrast and thin atmospheres with high mean molecular weight. Recently, a new class of habitable exoplanets, called Hycean worlds, has been proposed, defined as temperate ocean-covered worlds with H₂-rich atmospheres. Their large sizes and extended atmospheres, compared to rocky planets of the same mass, make Hycean worlds significantly more accessible to atmospheric spectroscopy with JWST. Here we report a transmission spectrum of the candidate Hycean world K2-18 b, observed with the JWST NIRISS and NIRSpec instruments in the 0.9–5.2 μm range. The spectrum reveals strong detections of methane (CH₄) and carbon dioxide (CO₂) at 5σ and 3σ confidence, respectively, with high volume mixing ratios of ∼1% each in a H₂-rich atmosphere. The abundant CH₄ and CO₂, along with the nondetection of ammonia (NH₃), are consistent with chemical predictions for an ocean under a temperate H₂-rich atmosphere on K2-18 b. The spectrum also suggests potential signs of dimethyl sulfide (DMS), which has been predicted to be an observable biomarker in Hycean worlds, motivating considerations of possible biological activity on the planet. The detection of CH₄ resolves the long-standing missing methane problem for temperate exoplanets and the degeneracy in the atmospheric composition of K2-18 b from previous observations. We discuss possible implications of the findings, open questions, and future observations to explore this new regime in the search for life elsewhere.

We investigate a new class of habitable planets composed of water-rich interiors with massive oceans underlying H₂-rich atmospheres, referred to here as Hycean worlds. With densities between those of rocky super-Earths and more extended mini-Neptunes, Hycean planets can be optimal candidates in the search for exoplanetary habitability and may be abundant in the exoplanet population. We investigate the bulk properties (masses, radii, and temperatures), potential for habitability, and observable biosignatures of Hycean planets. We show that Hycean planets can be significantly larger compared to previous considerations for habitable planets, with radii as large as 2.6 R _⊕ (2.3 R _⊕) for a mass of 10 M _⊕ (5 M _⊕). We construct the Hycean habitable zone (HZ), considering stellar hosts from late M to Sun-like stars, and find it to be significantly wider than the terrestrial-like HZ. While the inner boundary of the Hycean HZ corresponds to equilibrium temperatures as high as ∼500 K for late M dwarfs, the outer boundary is unrestricted to arbitrarily large orbital separations. Our investigations include tidally locked “Dark Hycean” worlds that permit habitable conditions only on their permanent nightsides and “Cold Hycean” worlds that see negligible irradiation. Finally, we investigate the observability of possible biosignatures in Hycean atmospheres. We find that a number of trace terrestrial biomarkers that may be expected to be present in Hycean atmospheres would be readily detectable using modest observing time with the James Webb Space Telescope (JWST). We identify a sizable sample of nearby potential Hycean planets that can be ideal targets for such observations in search of exoplanetary biosignatures.

Exoplanets orbiting M-dwarfs present a valuable opportunity for their detection and atmospheric characterization. This is evident from recent inferences of H₂O in such atmospheres, including that of the habitable-zone exoplanet K2-18b. With a bulk density between Earth and Neptune, K2-18b may be expected to possess a H/He envelope. However, the extent of such an envelope and the thermodynamic conditions of the interior remain unexplored. In the present work, we investigate the atmospheric and interior properties of K2-18b based on its bulk properties and its atmospheric transmission spectrum. We constrain the atmosphere to be H₂-rich with a H₂O volume mixing ratio of 0.02%–14.8%, consistent with previous studies, and find a depletion of CH₄ and NH₃, indicating chemical disequilibrium. We do not conclusively detect clouds/hazes in the observable atmosphere. We use the bulk parameters and retrieved atmospheric properties to constrain the internal structure and thermodynamic conditions in the planet. The constraints on the interior allow multiple scenarios between rocky worlds with massive H/He envelopes and water worlds with thin envelopes. We constrain the mass fraction of the H/He envelope to be ≲6%; spanning ≲10⁻⁵ for a predominantly water world to ∼6% for a pure iron interior. The thermodynamic conditions at the surface of the H₂O layer range from the supercritical to liquid phases, with a range of solutions allowing for habitable conditions on K2-18b. Our results demonstrate that the potential for habitable conditions is not necessarily restricted to Earth-like rocky exoplanets.

The recent inference of sulfur dioxide (SO₂) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations^1–3 suggests that photochemistry is a key process in high-temperature exoplanet atmospheres⁴. This is because of the low (<1 ppb) abundance of SO₂ under thermochemical equilibrium compared with that produced from the photochemistry of H₂O and H₂S (1–10 ppm)^4–9. However, the SO₂ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO₂ absorption bands at different wavelengths is needed to better constrain the SO₂ abundance. Here we report the detection of SO₂ spectral features at 7.7 and 8.5 μm in the 5–12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)¹⁰. Our observations suggest an abundance of SO₂ of 0.5–25 ppm (1σ range), consistent with previous findings⁴. As well as SO₂, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1–8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI Low Resolution Spectrometer observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000× solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities ≤300× solar due to their large corresponding molecular feature amplitudes, preferring values ≥1000× solar and column haze production rates ≥10 ⁻¹⁰ g cm ⁻² s ⁻¹ . The steam atmosphere scenario with similarly high haze production rates also exhibits sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights ≥15 g mol ⁻¹ are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b’s atmosphere would likely require multiple transits and eclipses using JWST across the near- and mid-infrared, potentially complemented by ground-based high-resolution transmission spectroscopy.