Rasmus Barfod

Rasmus Barfod

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Rasmus Barfod

Haldor Topsoe, Haldor Topsøes Allé 1, DK-2800 Kgs. Lyngby, Denmark

Research Focus & Metrics

Academic Career Length

20Years (2007-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 January 2007 in Journal of the Electrochemical Society
Verified
Journal Article
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RBRasmus Barfod
Rasmus Barfod
MMMogens Mogensen
Mogens Mogensen
TKTrine Klemenso̸
Trine Klemenso̸
Anke HagenAnke Hagen
Anke Hagen
YLYi-Lin Liu
Yi-Lin Liu
PHPeter Vang Hendriksen
Peter Vang Hendriksen
Anode-supported thin electrolyte cells are studied by electrochemical impedance spectroscopy (EIS). The aim is to describe how the losses of this type of cells are distributed at low current density (around open-circuit voltage) as a function of temperature. An equivalent circuit consisting of an inductance, a serial resistance <mml:math display="inline"><mml:mrow><mml:mo>(</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi>s</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math>(Rs) , and five arcs to describe the polarization resistance is suggested. This equivalent circuit is based on previous studies of single electrodes in three-electrode and two-electrode symmetric cell setups. The equivalent circuit components have been assigned to the electrode processes, and the assignments were verified by extensive full cell studies in which the partial pressure of reactant gases on both the electrodes as well as temperature was systematically varied with the aim to identify frequency regions which are dominated by an electrode specific process. Furthermore, the model is applied on a good performing cell with area specific resistance <mml:math display="inline"><mml:mrow><mml:mo>(</mml:mo><mml:mi>ASR</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mn>0.15</mml:mn><mml:mspace width="0.3em"></mml:mspace><mml:mi mathvariant="normal">Ω</mml:mi><mml:mspace width="0.3em"></mml:mspace><mml:msup><mml:mi>cm</mml:mi><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math>(ASR)=0.15Ωcm2 at <mml:math display="inline"><mml:mrow><mml:mn>850</mml:mn><mml:mo>°</mml:mo><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math>850°C and a poor performing cell with <mml:math display="inline"><mml:mrow><mml:mi>ASR</mml:mi><mml:mo>=</mml:mo><mml:mn>0.29</mml:mn><mml:mspace width="0.3em"></mml:mspace><mml:mi mathvariant="normal">Ω</mml:mi><mml:mspace width="0.3em"></mml:mspace><mml:msup><mml:mi>cm</mml:mi><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math>ASR=0.29Ωcm2 at the same temperature. Both cells were fabricated using nominally the same procedure. The EIS analysis indicated that the difference in performance originates from microstructural differences on the cathode. This is further supported by the observation of large differences in the cathode microstructure by scanning electron microscope.

1 December 2015 in Journal of Power Sources
Verified
Journal Article
Closed access
Anke HagenAnke Hagen
Anke Hagen
JHJens Valdemar Thorvald Høgh
Jens Valdemar Thorvald Høgh
RBRasmus Barfod
Rasmus Barfod