The spectral characterization of land covers using earth observation technologies is a constantly developing and highly demanded field for the study and monitoring of natural resources, agricultural activity, and urban planning. In urban applications, these technologies are gaining ground in obtaining highly detailed primary information through field spectroscopy, with key applications in risk management, cadastral management, and climate change. This study presents the spectral characterization of eight common building roof materials, based on reflectance measurements in the 350–2500 nanometer range, for a total of 938 effective spectral signatures of eight roof materials captured across 156 sampling points in five Colombian cities during the first semester of 2025. The methodology included a specific sampling and subsampling design to capture spectral variance at the roof level, using a NaturaSpec spectroradiometer and a contact probe. An analysis of the spectral library, which included descriptive and feature importance analysis using Random Forest and Spectral Normal Variate Normalization, revealed that the material types characterized in all five cities exhibit significant similarities in their absorption patterns, trends, and peaks, with the exception of translucent materials such as plastics. Furthermore, while the spectral response is dominated by building roofs color in the visible region, the short-wave infrared region has a greater spectral separability of material type and conservation status. These spectral data and, their corresponding metadata, were captured and cataloged to contribute to the construction of a National Spectral Bank, with the goal of consolidating a comprehensive Colombian spectral database for applications in agriculture, environmental monitoring, and urban management.