The nature of the group 13 metal halides strongly affects the structure of their complexes with 4,4′-bipy.

A new convenient approach to the synthesis of useful N-heterocyclic carbene complexes of group 13 metals was successfully developed. We demonstrate that air-stable copper(I) diaminocarbene complexes are excellent carbene transfer reagents for the synthesis of (IMes or IPr)MCl₃ with high yields (M = Al, Ga). Use of this simple method allowed for the first time to obtain (IPr)AlCl₃, inaccessible via a free carbene route. In contrast to copper complexes, under the same conditions the more commonly used silver analog (IPr)AgCl reacts with MCl₃ (M = Al, Ga, In) yielding only the homoleptic cationic complexes [(IPr)₂Ag]⁺MCl₄ ⁻.

Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11B NMR and IR spectroscopy...