In this work, a 3D printed polymer–metal soft-magnetic composite was developed and characterized for its material, structural, and functional properties. The material comprises acrylonitrile butadiene styrene (ABS) as the polymer matrix, with up to 40 vol. % stainless steel micropowder as the filler. The composites were rheologically analyzed and 3D printed into tensile and flexural test specimens using a commercial desktop 3D printer. Mechanical characterization revealed a linearly decreasing trend of the ultimate tensile strength (UTS) and a sharp decrease in Young’s modulus with increasing filler content. Four-point bending analysis showed a decrease of up to 70% in the flexural strength of the composite and up to a two-factor increase in the secant modulus of elasticity. Magnetic hysteresis characterization revealed retentivities of up to 15.6 mT and coercive forces of up to 4.31 kA/m at an applied magnetic field of 485 kA/m. The composite shows promise as a material for the additive manufacturing of passive magnetic sensors and/or actuators.

A process for the development, characterization and correlation of composite materials for 3D printing is presented, alongside the processing of a polymer-ceramic functional composite using fused deposition modeling (FDM). The composite was developed using acrylonitrile butadiene styrene (ABS) as the matrix material filled with barium titanate (BT) micro-powder up to 35 vol % (74.2 wt %). The ABS-BT composites exhibited a shear thinning behavior with increasing ceramic content. The composite was 3D printed into structural and functional test samples using FDM by adapting and optimizing the print parameters. Structural characterization revealed increasingly brittle behavior at higher filler ratios, with the ultimate tensile strength falling from 25.5 MPa for pure ABS to 13.7 MPa for the ABS-35 vol % BT composite. Four-point flexural tests showed a similar decrease in flexural strength with increasing ceramic content. Functional characterization revealed an increase in the relative permittivity at 200 kHz from 3.08 for pure ABS to 11.5 for the composite with 35 vol % BT. These results were correlated with the Maxwell-Garnett and Jayasundere-Smith effective medium models. The process described in this work can be used for other 3D printing processes and provides a framework for the rapid prototyping of functional composites into functional parts with reliable properties. The ABS-BT composite shows promise as a functional dielectric material, with potential applications as capacitors and light-weight passive antennas.

Additive manufacturing, or nowadays more popularly entitled as 3D printing, enables a fast realization of polymer, metal, ceramic or composite devices, which often cannot be fabricated with conventional methods. One critical issue for a continuation of this success story is the generation of multi-material devices. Whilst in fused filament fabrication or 3D InkJet printing, commercial solutions have been realized, in stereolithography only very few attempts have been seen. In this work, a comprehensive approach, covering the construction, material development, software control and multi-material printing is presented for the fabrication of structural details in the micrometer range. The work concludes with a critical evaluation and possible improvements.

The thermoplastic polymer polyether ether ketone (PEEK) offers thermal and mechanical properties comparable to thermosetting polymers, while also being thermally re-processable and recyclable as well as compatible with fused filament fabrication (FFF). In this study, the feasibility of joining additively manufactured PEEK in pure and short carbon-fiber-reinforced form (CF-PEEK) is investigated. Coupon-level samples for both materials were fabricated using FFF with tailored integrated welding surfaces in the form of two different energy director (ED) shapes and joined through ultrasonic polymer welding. Using an energy-driven joining process, the two materials were systematically investigated with different welding parameters, such as welding force, oscillation amplitude and welding power, against the resulting weld quality. The strengths of the welded bonds were characterized using lap-shear tests and benchmarked against the monotonic properties of single 3D-printed samples, yielding ultimate lap-shear forces of $2.17$$\mathrm{k}$$\mathrm{N}$ and $1.97$$\mathrm{k}$$\mathrm{N}$ and tensile strengths of $3.24$$\mathrm{M}$$\mathrm{Pa}$ and $3.79$$\mathrm{M}$$\mathrm{Pa}$ for PEEK and CF-PEEK, respectively. The weld surfaces were microscopically imaged to characterize the failure behaviors of joints welded using different welding parameters. Samples welded with optimized welding parameters exhibited failures outside the welded region, indicating a higher weld-strength compared to that of the bulk. This study lays the foundation for using ultrasonic welding as a glue-free method to join 3D-printed high-performance thermoplastics to manufacture large load-bearing, as well as non-load-bearing, structures, while minimizing the time and cost limitations of FFF as a fabrication process.