A novel piezoelectric paper based on antimony sulfoiodide (SbSI) nanowires is reported. The composite of tough sonochemically produced SbSI nanowires (with lateral dimensions 10–100 nm and length up to several micrometers) with very flexible cellulose leads to applicable, elastic material suitable to use in fabrication of, for example, piezoelectric nanogenerators. For mechanical energy harvesting, cellulose/SbSI nanocomposite may be used. Due to its high values of electromechanical coefficient (k₃₃ = 0.9) and piezoelectric coefficient (d₃₃ = 1 × 10⁻⁹ C/N), SbSI is a very attractive material for such devices. The preliminary investigations of a simple cellulose/SbSI nanogenerator for shock pressure (p = 3 MPa) and sound excitation (f = 175 Hz, L_p = 90 dB) allowed to determine its open circuit voltage 2.5 V and 24 mV, respectively. For a load resistance equal to source impedance (Z_S = 2.90(11) MΩ), maximum output power density (P_L = 41.5 nW/cm³ for 0.05-mm-thick sheet of this composite) of the cellulose/SbSI nanogenerator was observed. Cellulose/SbSI piezoelectric paper may also be useful to construct gas nanosensors and actuators.

In this paper, ferroelectric antimony sulfoiodide (SbSI) nanowires have been used to produce composites for device fabrication, which can be used for energy harvesting and sensors. SbSI is a very useful material for nanogenerators and nanosensors in which the high values of the piezoelectric coefficient (d₃₃ = 650 pC/N) and the electromechanical coefficient (k₃₃ = 0.9) are essential. Alternatively, cellulose and epoxy resin were matrix materials in these composites, whereas SbSI nanowires fill the matrix. Piezoelectric response induced by vibrations has been presented. Then, a composite with an epoxy resin has been used as an element to construct a fiber-reinforced polymer piezoelectric sensor. For the first time, comparison of piezoelectric properties of cellulose/SbSI and epoxy resin/SbSI nanocomposite has been presented. The influence of concentration of SbSI nanowires for properties of epoxy resin/SbSI nanocomposite and in a fiber-reinforced polymer based on them has also been shown. Results of aligning the SbSI nanowires in the epoxy matrix during a curing process have been presented as well.

A novel polymeric, polyacrylonitrile (PAN) nanofibers containing ferroelectric and semiconducting antimony sulfoiodide (SbSI) have been made by electrospinning. SbSI nanowires, used as the filler, have been prepared sonochemically from antimony sulphide (Sb₂S₃) and antimony tri-iodide (SbI₃) for the first time. Nanocrystalline SbSI has been fabricated in ethanol under ultrasonic irradiation (20kHz, 565W/cm²) at 323K within 2h. The products have been characterized by using techniques such as powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, high-resolution transmission electron microscopy, selected area electron diffraction and optical diffuse reflection as well as transmission spectroscopy. The good quality of the nanocrystals and their dispersion in the nanofiber's volume is important because this material is attractive for nanogenerators due to its ferroelectric and piezoelectric properties. The amplitude of the voltage pulse, generated under shock pressure of 3.0MPa, has reached 180V in the prototype PAN/SbSI piezoelectric nanogenerator. The peak output voltage of about 0.2V was measured in bending/releasing conditions with the deformation frequency of 1Hz.