Metal–organic frameworks (MOFs) have emerged as a transformative class of materials, offering unprecedented versatility in applications ranging from energy storage to environmental remediation and photocatalysis.

In this study, co-precipitation synthesis of natural clay (NC) with Co₃O₄ nanoparticles (NPs) is carried out to elaborate the super NC@Co₃O₄ nanocomposites with admirable salinity confrontation, environmental stability and reusability, to eliminate heavy metal pollution such as toxic Pb(II) and Cd(II) ions. The advantages of using the NC@Co₃O₄ adsorbent are easy synthesis and biocompatibility. In addition, NC@Co₃O₄ can keep an excellent adsorption capacity by taking into account various environmental parameters such as the pH solution, NC@Co₃O₄ dose, adsorption process time and the initial heavy metals concentration. Furthermore, FTIR, XRD, TGA, SEM-EDS, TEM and AFM analyses were performed to confirm NC@Co₃O₄ nanocomposites synthesis and characterisation. The adsorption efficiencies of Pb(II) and Cd(II) ions by NC@Co₃O₄ nanocomposites were demonstrated to be up to 86.89% and 82.06% respectively. Regarding the adsorption from water onto the NC@Co₃O₄ nanocomposites, kinetics data were well fitted with PSO kinetic model, whereas a good agreement was found between the equilibrium adsorption and theoretical Langmuir isotherm model leading to maximum adsorption capacities of 55.24 and 52.91 mg/g, for Pb(II) and Cd(II) respectively. Monte Carlo (MC) simulations confirmed the spontaneous of this adsorption based on the negative values of E_ads. The MC simulations were performed to highlight the interactions occurring between heavy metal ions and the surface of NC@Co₃O₄ nanocomposites, these were well correlated with the experimental results. Overall the study showed that NC@Co₃O₄ nanoadsorbents have strongly versatile applications and are well designed for pollutant removal from wastewater due to their unique adsorptive properties.

Biofilm formation on food packaging surfaces is a major issue in the industry, as it leads to contamination, reduces shelf life, and poses risks to human health. To mitigate these effects, developing smart coatings that can actively sense and combat microbial growth has become a critical research focus. This study is motivated by the need for intelligent packaging solutions that integrate antimicrobial agents and sensors for real‐time contamination detection. It is hypothesized that combining conducting polymers (CPs) with nanomaterials can enhance antimicrobial efficacy while maintaining the mechanical integrity and environmental stability required for food packaging applications. Through the application of numerous technologies like surface modification, CP–nanoparticle integration, and multilayered coating, the antimicrobial performance and sensor capabilities of these materials were analyzed. Case studies showed a 90% inhibition of bacterial growth and a tenfold decrease in viable bacterial counts with AgNPs incorporation, extending strawberries’ shelf life by 40% and maintaining fish freshness for an additional 5 days. Moreover, multilayered CP coatings in complex systems have been shown to reduce oxidative spoilage in nuts and dried fruits by up to 85%, while maintaining the quality of leafy greens for up to 3 weeks under suboptimal conditions. Environmental assessments indicated a 30% reduction in carbon footprint when CP coatings were combined with biodegradable polymers, contributing to a more transparent and reliable food supply chain. CP‐based films integrated with intelligent sensors exhibit high sensitivity, detecting ammonia concentrations below 500 ppb, and offer significant selectivity for sensing hazardous gases. These findings indicate that CP‐based smart coatings markedly enhance food safety and sustainability in packaging applications.

In recent decades, food-packaging markets have attracted researchers' interest in many ways because such industries can directly affect human health. In this framework, the present study emphasizes the interesting and smart properties provided by new nanocomposites based on conducting polymers (CPs), silver nanoparticles (AgNPs), and cellulose fibers (CFs) and their possible applications as active food packaging. Polyaniline and poly(3,4-ethylenedioxythiophene) containing AgNPs were elaborated on via a simple one-step in situ chemical oxidative polymerization on CFs. Spectroscopic and microscopic characterization allowed a full discussion of the morphology and chemical structure of the nanocomposites and confirmed the successful polymerization of the monomer as well as the incorporation of AgNPs into the CP-based formulation. This study aims to demonstrate that it is possible to produce a highly efficient package with enhanced protective properties. Thus, the synthesized nanocomposites were tested as volatile organic compounds, sensors, and antibacterial and antioxidant agents. It is shown that the elaborated materials can, on the one hand, inhibit the development of biofilms and decrease the oxidation reaction rate of foodstuffs and, on the other hand, detect toxic gases generated by spoiled food. The presented method has unlocked massive opportunities for using such formulations as an interesting alternative for classical food containers. The smart and novel properties offered by the synthesized composites can be operated for future industrial applications to prevent any degradation of the packaged products by offering optimum protection and creating an atmosphere that can extend the shelf life of foodstuffs.