The effect of structural defects and framework flexibility on the water adsorption in CAU-10-H was explored by a grand canonical Monte Carlo simulation.

The paper presents laboratory and in situ research data on interaction of geomechanical and physicochemical processes in Kuzbass coal of various ranks, considering temperature effect. Under analysis is the relation of stress-strain state, temperature and infrared radiation of coal. The authors study the role of temperature and microstructure of coal in energy and mass exchange processes (variation of mass, volatile yield, specific surface, internal energy of methane adsorption capacity decrease and moisture content). Interrelation of outburst hazard and fire hazard in coal is discussed from the viewpoint of uniform stagewise thermomechanics and thermochemistry of coal behavior in the course of coal formation and extraction. The article introduces a generalized factor for quantitative description of petrographic properties of coal. Using this factor, the authors classify and describe petrographic groups of Kuzbass coal.

The H₂ sorption properties of the aluminophosphate zeolites AlPO-5, AlPO-31, AlPO-11, AlPO-36, and AlPO-8 at 77 K have been investigated. A series of H₂ adsorption isotherms has been obtained for cylindrical micropore channels in the aluminophosphate zeolites. The absolute values of the amount adsorbed α(P) for the mesoporous aluminophosphate materials and the effective density of adsorbed H₂ in the micropore space β*(P, d) have been determined. It has been demonstrated experimentally that the sorbate density depends on the size of the micropore channel of the zeolite d. Hydrogen sorption isotherms have been calculated from experimental isotherms. A procedure allowing β*(P, d) to be estimated for intermediate d values is presented.