Advanced anodic SnO₂ nanoporous structures decorated with Cu₂O nanoparticles (NPs) were employed for creatinine detection. Anodization of electropolished Sn sheets in 0.3 M aqueous oxalic acid electrolyte under continuous stirring produced complete open top, crack-free, and smooth SnO₂ nanoporous structures. Structural analyses confirm the high purity of rutile SnO₂ with successful functionalization of Cu₂O NPs. Morphological studies revealed the formation of self-organized and highly-ordered SnO₂ nanopores, homogeneously decorated with Cu₂O NPs. The average diameter of nanopores is ∼35 nm, while the average Cu₂O particle size is ∼23 nm. Density functional theory results showed that SnO₂@Cu₂O hybrid nanostructures are energetically favorable for creatinine detection. The hybrid nanostructure electrode exhibited an ultra-high sensitivity of around 24343 μA mM^-1 cm^-2 with an extremely lower detection limit of ∼0.0023 μM, a fast response time (less than 2 s), and wide linear detection ranges of 2.5-45 μM and 100 μM to 15 mM toward creatinine. This is ascribed to the creation of highly active surface sites as a result of Cu₂O NP functionalization, SnO₂ band gap diminution, and the formation of heterojunction and Cu(1)/Cu(ll)-creatinine complexes through secondary amines which occur in the creatinine structure. The real-time analysis of creatinine in blood serum by the fabricated electrode evinces the practicability and accuracy of the biosensor with reference to the commercially existing creatinine sensor. The proposed biosensor demonstrated excellent stability, reproducibility, and selectivity, which reflects that the SnO₂@Cu₂O nanostructure is a promising candidate for the non-enzymatic detection of creatinine.

In this study, we fabricated a nanoporous oxide layer by anodization to improve corrosion resistance of type 304 stainless steel (SS) gas tungsten arc weld (GTAW). Subsequent heat treatment was performed to eliminate any existing fluorine in the nanoporous oxide layer. Uniform structures and compositions were analyzed with field emission scanning electron microscope (FESEM) and X-ray diffractometer (XRD) measurements. The corrosion resistance of the treated SS was evaluated by applying a potentiodynamic polarization (PDP) technique and electrochemical impedance spectroscopy (EIS). Surface morphologies of welded SS with and without treatment were examined to compare their corrosion behaviors. All results indicate that corrosion resistance was enhanced, making the treatment process highly promising.

A facile route to producing non-stoichiometric silicon suboxide nanoparticles (SiO_x NPs, 0 < x < 1) with an adjustable oxygen content is proposed. The process is based on electrochemical anodization involving the application of a strong electric field near the surface of a Si electrode to directly convert the Si electrode into SiO_x NPs. The difference in ion mobility between oxygen species (O²⁻ and OH⁻), formed during anodization, causes the production of non-stoichiometric SiO_x on the surface of the Si while, simultaneously, fluoride ions in the electrolyte solution etch the formed SiO_x layer, generating NPs under the intense electric field. The adjustment of the applied voltage and anodization temperature alters the oxygen content and the size of the SiO_x NPs, respectively, allowing the characteristics of the NPs to be readily controlled. The proposed approach can be applied for mass production of SiO_x NPs and is highly promising in the field of batteries and optoelectronics.

Hybrid electrodes comprising metal oxides and vertically aligned graphene (VAG) are promising for high-performance supercapacitor applications because they enhance the synergistic effect owing to the large contact area between the two constituent materials. However, it is difficult to form metal oxides (MOs) up to the inner surface of a VAG electrode with a narrow inlet using conventional synthesis methods. Herein, we report a facile approach to fabricate SnO₂ nanoparticle-decorated VAG electrodes (SnO₂@VAG) with excellent areal capacitance and cyclic stability using sonication-assisted sequential chemical bath deposition (S-SCBD). The sonication treatment during the MO decoration process induced a cavitation effect at the narrow inlet of the VAG electrode, allowing the precursor solution to reach the inside of the VAG surface. Furthermore, the sonication treatment promoted MO nucleation on the entire VAG surface. Thus, the SnO₂ nanoparticles uniformly covered the entire electrode surface after the S-SCBD process. SnO₂@VAG exhibited an outstanding areal capacitance (4.40 F cm^-2) up to 58% higher than that of VAG electrodes. The symmetric supercapacitor with SnO₂@VAG electrodes showed an excellent areal capacitance (2.13 F cm^-2) and a cyclic stability of 90% after 2000 cycles. These results suggest a new avenue for sonication-assisted fabrication of hybrid electrodes in the field of energy storage.