In recent years, there has been a significant accumulation of waste in the environment, and it is expected that this accumulation may increase in the years to come. Waste disposal has massive effects on the environment and can cause serious environmental problems. Thus, the development of a waste treatment system is of major importance. Agro-industrial wastewater and waste residues are mainly rich in organic substances, lignocellulose, hemicellulose, lignin, and they have a relatively high amount of energy. As a result, an effective agro-waste treatment system has several benefits, including energy recovery and waste stabilization. To reduce the impact of the consumption of fossil energy sources on our planet, the exploitation of renewable sources has been relaunched. All over the world, efforts have been made to recover energy from agricultural waste, considering global energy security as the final goal. To attain this objective, several technologies and recovery methods have been developed in recent years. The microbial fuel cell (MFC) is one of them. This review describes the power generation using various types of agro-industrial wastewaters and agricultural residues utilizing MFC. It also highlights the techno-economics and lifecycle assessment of MFC, its commercialization, along with challenges.

Increasing untreated environmental outputs from industry and the rising human population have increased the burden of wastewater and other waste streams on the environment. The most prevalent wastewater treatment methods include the activated sludge process, which requires aeration and is, therefore, energy and cost-intensive. The current trend towards a circular economy facilitates the recovery of waste materials as a resource. Along with the amount, the complexity of wastewater is increasing day by day. Therefore, wastewater treatment processes must be transformed into cost-effective and sustainable methods. Microbial fuel cells (MFCs) use electroactive microbes to extract chemical energy from waste organic molecules to generate electricity via waste treatment. This review focuses use of MFCs as an energy converter using wastewater from various sources. The different substrate sources that are evaluated include industrial, agricultural, domestic, and pharmaceutical types. The article also highlights the effect of operational parameters such as organic load, pH, current, and concentration on the MFC output. The article also covers MFC functioning with respect to the substrate, and the associated performance parameters, such as power generation and wastewater treatment matrices, are given. The review also illustrates the success stories of various MFC configurations. We emphasize the significant measures required to fill in the gaps related to the effect of substrate type on different MFC configurations, identification of microbes for use as biocatalysts, and development of biocathodes for the further improvement of the system. Finally, we shortlisted the best performing substrates based on the maximum current and power, Coulombic efficiency, and chemical oxygen demand removal upon the treatment of substrates in MFCs. This information will guide industries that wish to use MFC technology to treat generated effluent from various processes.

Electro-fermentation (EF) is an upcoming technology that can control the metabolism of exoelectrogenic bacteria (i.e., bacteria that transfer electrons using an extracellular mechanism). The fermenter consists of electrodes that act as sink and source for the production and movement of electrons and protons, thus generating electricity and producing valuable products. The conventional process of fermentation has several drawbacks that restrict their application and economic viability. Additionally, metabolic reactions taking place in traditional fermenters are often redox imbalanced. Almost all metabolic pathways and microbial strains have been studied, and EF can electrochemically control this. The process of EF can be used to optimize metabolic processes taking place in the fermenter by controlling the redox and pH imbalances and by stimulating carbon chain elongation or breakdown to improve the overall biomass yield and support the production of a specific product. This review briefly discusses microbe-electrode interactions, electro-fermenter designs, mixed-culture EF, and pure culture EF in industrial applications, electro methanogenesis, and the various products that could be hence generated using this process.