Given the problems related to drinking water supplies in rural and economically disadvantaged regions, point-of-use disinfection technologies are a viable alternative to improve access to drinking. Electrochlorinators are devices that produce chlorine-based disinfectants onsite via the electrolysis of a sodium chloride solution. In this research, we have constructed an innovative laboratory-scale three-compartment cell that includes two ion exchange membranes, fixed between two electrodes; in the anodic compartment, an acidic mixture of chlorine-based species (Cl₂, HClO, HCl and ClO⁻) is obtained, and, in the cathodic compartment, an alkaline solution is present (NaOH and hydrogen gas), while the central compartment is fed with a sodium chloride solution. The Taguchi methodology was used to examine the impact of the process operating conditions on the results obtained. The effects of the electrical potential levels (4.5, 6 and 7 V), electrolysis times (30, 60 and 90 min) and initial sodium chloride concentrations (5, 15 and 30 g/L) on the physical and chemical characteristics (concentrations of available chlorine and sodium hydroxide and pH of the solutions) and energy consumption were investigated. Variations in the electrical potential significantly influenced the concentration levels of active chlorine and sodium hydroxide produced, as well as the pH values of the respective solutions. The most favorable conditions for the production of electrolyzed water were an electrical potential of 7 volts, an electrolysis time of 90 min and a concentration of 30 g/L of sodium chloride, which was verified by ANOVA. The maximum concentration of active chlorine reached 290 mg/L and that of sodium hydroxide reached 1450 mg/L without the presence of hypochlorite ions under the best synthesis conditions. The energy consumption was 18.6 kWh/kg Cl₂ and 4.4 kWh/kg NaOH, while the average electric current efficiency for sodium hydroxide formation reached 88.9%. Similarly, the maximum conversion of chloride ions reached 24.37% under the best operating conditions.

The desalination of brackish and seawater has emerged as a critical strategy to address growing water scarcity in regions experiencing water stress, particularly within the context of sustainable water resource management. Among available technologies, forward osmosis (FO) has gained increasing attention due to its potential for lower energy consumption and reduced environmental impact compared to conventional desalination processes. In this study, commercial HFFO₂ (Aquaporin Inside) membrane from FO was used. A complete factorial design with three factors was used: feed solution concentration (1.5 and 3 g/L NaCl), draw solution concentration (15, 25, and 35 g/L NaCl), and feed solution flow rate (600 and 1000 mL/min) on the percentage of recovery and water flux. Tests showed that as the feed concentration decreases from 3 to 1.5 g/L of NaCl, water recovery improves by 23.6%. The results revealed that increasing the concentration of the draw solution from 15 to 25 g/L of NaCl increased water recovery by 22.2%. However, for a concentration variation of 25 to 35 g/L, this increase is insignificant at 0.92%. The results showed that, with a concentration of 1.5 g/L of NaCl, a feed flow rate of 1000 mL/min, and a concentration of 25 g/L of NaCl as the draw solution, a higher water recovery rate (95.4839%) was achieved. Similarly, average water flux values of 2.18, 2.43, and 2.68 $L{m}^{-2}{h}^{-1}$ were observed when using draw solutions of 15, 25, and 35 g/L of NaCl, respectively. In addition, increasing the FS flow rate slightly reduces water recovery (from 76.04% to 74.06%). Consequently, the forward osmosis process has proven to be effective, practical, viable, and environmentally friendly for water desalination, as well as being applicable to the treatment of wastewater with high electrical conductivity.