In this paper, we review various novel/modified interfacial polymerization (IP) techniques for the fabrication of polyamide (PA) thin film composite (TFC)/thin film nanocomposite (TFN) membranes in both pressure-driven and osmotically driven separation processes. Although conventional IP technique is the dominant technology for the fabrication of commercial nanofiltration (NF) and reverse osmosis (RO) membranes, it is plagued with issues of low membrane permeability, relatively thick PA layer and susceptibility to fouling, which limit the performance. Over the past decade, we have seen a significant growth in scientific publications related to the novel/modified IP techniques used in fabricating advanced PA-TFC/TFN membranes for various water applications. Novel/modified IP lab-scale studies have consistently, so far, yielded promising results compared to membranes made by conventional IP technique, in terms of better filtration efficiency (increased permeability without compensating solute rejection), improved chemical properties (crosslinking degree), reduced surface roughness and the perfect embedment of nanomaterials within selective layers. Furthermore, several new IP techniques can precisely control the thickness of the PA layer at sub-10 nm and significantly reduce the usage of chemicals. Despite the substantial improvements, these novel IP approaches have downsides that hinder their extensive implementation both at the lab-scale and in manufacturing environments. Herein, this review offers valuable insights into the development of effective IP techniques in the fabrication of TFC/TFN membrane for enhanced water separation.

Many studies indicated that phthalates, a common plasticizer, lurk silently in water bodies and can potentially harm living organisms. Therefore, removing phthalates from water sources prior to consumption is crucial. This study aims to evaluate the performance of several commercial nanofiltrations (NF) (i.e., NF3 and Duracid) and reverse osmosis (RO) membranes (i.e., SW30XLE and BW30) in removing phthalates from simulated solutions and further correlate the intrinsic properties of membranes (e.g., surface chemistry, morphology, and hydrophilicity) with the phthalates removal. Two types of phthalates, i.e., dibutyl phthalate (DBP) and butyl benzyl phthalate (BBP), were used in this work, and the effects of pH (ranging from 3 to 10) on the membrane performance were studied. The experimental findings showed that the NF3 membrane could yield the best DBP (92.5–98.8%) and BBP rejection (88.7–91.7%) regardless of pH, and these excellent results are in good agreement with the surface properties of the membrane, i.e., low water contact angle (hydrophilicity) and appropriate pore size. Moreover, the NF3 membrane with a lower polyamide cross-linking degree also exhibited significantly higher water flux compared to the RO membranes. Further investigation indicated that the surface of the NF3 membrane was severely covered by foulants after 4-h filtration of DBP solution compared to the BBP solution. This could be attributed to the high concentration of DBP presented in the feed solution owing to its high-water solubility (13 ppm) compared to BBP (2.69 ppm). Further research is still needed to study the effect of other compounds (e.g., dissolved ions and organic/inorganic matters that might be present in water) on the performance of membranes in removing phthalates.