The laser powder bed fusion (LPBF) is an additive manufacturing technology involving a gradual build-on of layers to form a complete component according to a computer-aided design. The LPBF process boasts of manufacturing value-added parts with higher accuracy and complex geometries for the transport, aviation, energy, and biomedical industries. TiAl-based alloys and high-entropy alloys (HEAs) are two materials envisaged as potential replacements of nickel-based superalloys for high temperature structural applications. The success of these materials hinge on optimization and implementation of tailored microstructures through controlled processing and appropriate alloy manipulations that can promote and stabilize new microstructures. Therefore, it is important to understand the LPBF technique, and its associated microstructure-mechanical property relationships. This paper discusses the metallurgical sintering processes of LPBF, the effects of process parameters on densification, microstructures, and mechanical properties of LPBFed TiAl-based alloys and HEAs. This paper also, presents updates and future studies recommendations on the LPBFed TiAl-based alloys and HEAs.

Microstructural phase evolution during melting and casting depends on the rate of cooling, the collective mobility of constituent elements, and binary constituent pairs. Parameters used in mechanical alloying and spark plasma sintering, the initial structure of binary alloy pairs, are some of the factors that influence phase evolution in powder-metallurgy-produced HEAs. Factors such as powder flowability, laser power, powder thickness and shape, scan spacing, and volumetric energy density (VED) all play important roles in determining the resulting microstructure in additive manufacturing technology. Large lattice distortion could hinder dislocation motion in HEAs, and this could influence the microstructure, especially at high temperatures, leading to improved mechanical properties in some HEAs. Mechanical properties of some HEAs can be influenced through solid solution hardening, precipitation hardening, grain boundary strengthening, and dislocation hardening. Despite the HEA system showing reliable potential engineering properties if commercialized, there is a need to examine the effects that processing routes have on the microstructure in relation to mechanical properties. This review discusses these effects as well as other factors involved.