Preethanuj Preethalayam

Dr. Preethanuj Preethalayam

Chemistry, Uppsala University, Uppsala, Stockholm, Sweden
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Research Focus & Metrics

Academic Career Length

14Years (2013-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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2 February 2017 in Chemical Reviews
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Journal Article
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Preethanuj PreethalayamPreethanuj Preethalayam
Preethanuj Preethalayam
KKK. Syam Krishnan
K. Syam Krishnan
STSreeja Thulasi
Sreeja Thulasi
SCS. Sarath Chand
S. Sarath Chand
JJJomy Joseph
Jomy Joseph
KRK. V. Radhakrishnan
K. V. Radhakrishnan

24 May 2018 in Analytical Chemistry
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Journal Article
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PSPadincharapad Sreedevi
Padincharapad Sreedevi
JNJyothi B. Nair
Jyothi B. Nair
Preethanuj PreethalayamPreethanuj Preethalayam
Preethanuj Preethalayam
BJBenadicta S. Jeeja
Benadicta S. Jeeja
CSCherumuttathu Suresh
Cherumuttathu Suresh
RVRamavarma Luxmi Varma
Ramavarma Luxmi Varma

5 October 2017 in Chemistry – A European Journal
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TKTarun Kumar
Tarun Kumar
FMFabien Massicot
Fabien Massicot
DHDominique HARAKAT
Dominique HARAKAT
SCSylviane Chevreux
Sylviane Chevreux
AMAgathe Martinez
Agathe Martinez
FJFlorian Jaroschik
Florian Jaroschik

19 June 2013 in Organic Letters
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Journal Article
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SCS. Sarath Chand
S. Sarath Chand
EJE. Jijy
E. Jijy
PPPraveen Prakash
Praveen Prakash
JSJan Szymoniak
Jan Szymoniak
Preethanuj PreethalayamPreethanuj Preethalayam
Preethanuj Preethalayam
KRK. V. Radhakrishnan
K. V. Radhakrishnan

1 November 2022 in Journal of Physical Organic Chemistry
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Preethanuj PreethalayamPreethanuj Preethalayam
Preethanuj Preethalayam
NVNathalie Proos Vedin
Nathalie Proos Vedin
SRSlavko Radenković
Slavko Radenković
HOHenrik Ottosson
Henrik Ottosson
The Baird‐aromaticity of BN/CC cyclooctatetraene isosteres (azaboracyclooctatetraenes) in their lowest triplet states (T1) has been explored through computations of various aromaticity indices that describe the different aspects of aromaticity (magnetic, electronic, energetic and geometric). While cyclooctatetraene (COT) is aromatic in its T1 state following Baird's 4n rule, we now reveal that the degrees of Baird‐aromaticity of its BN/CC isosteres vary with aromaticity aspect considered. The thermodynamically most stable octagonal B4N4H8 isomer, having an alternating B and N pattern (borazocine, B4N4COT‐A), is only weakly aromatic or nonaromatic in T1 according to energetic and electronic indices, while magnetic descriptors suggest it to have about two thirds the Baird‐aromaticity of T1 state COT (3COT). The extent of Baird‐aromaticity of intermediate BN/CC isosteres also varies markedly with aromaticity aspect considered. The strong aromaticity of 3B4N4COT‐A according to magnetic descriptors can be linked to the symmetries of the orbitals involved in the virtual transitions from occupied to unoccupied orbitals, which describe the response of a molecule in an external magnetic field. However, the magnetic aspect of T1 state Baird‐aromaticity (response aromaticity) is not related to the electronic and energetic aspects (intrinsic aromaticity), findings that underline earlier observations on differences between the various aspects of the aromaticity phenomenon (or phenomena).

20 June 2013 in Chemistry – A European Journal
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PPPraveen Prakash
Praveen Prakash
EJEliyan Jijy
Eliyan Jijy
Preethanuj PreethalayamPreethanuj Preethalayam
Preethanuj Preethalayam
PPPetri M. Pihko
Petri M. Pihko
SCSarngadharan Sarath Chand
Sarngadharan Sarath Chand
KRKokkuvayil V. Radhakrishnan
Kokkuvayil V. Radhakrishnan